1323140-53-9Relevant articles and documents
First stereoselective total synthesis of gallicynoic acids G and H
Radha Krishna, Palakodety,Anitha, Kadimi
, p. 1246 - 1253 (2011/09/14)
A stereoselective convergent total synthesis of two acetylenic acids, gallicynoic acid G (1) and H (2), is reported, involving asymmetric reduction of alkynones 3 and 4, respectively, with the Corey- Bakshi-Sibata (CBS) catalyst as a key step (Scheme 3), 3 and 4 being obtained from a common intermediate, the chiral alkynol 12 (Scheme 2). Copyright