1323140-48-2

Basic information

• Product Name: 1,1'-{{(1R,4S)-1-butyl-4-{8-[ (4-methoxybenzyl)oxy]butyl}octyl-2-yne-1,4-diyl}bis(oxy)}bis[(tert-butyl)dimethylsilane]
• Synonyms: 1,1'-{{(1R,4S)-1-butyl-4-{8-[ (4-methoxybenzyl)oxy]butyl}octyl-2-yne-1,4-diyl}bis(oxy)}bis[(tert-butyl)dimethylsilane]
• CAS NO: 1323140-48-2
• Molecular Weight: 619.089
• Mol File: 1323140-48-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1'-{{(1R,4S)-1-butyl-4-{8-[ (4-methoxybenzyl)oxy]butyl}octyl-2-yne-1,4-diyl}bis(oxy)}bis[(tert-butyl)dimethylsilane](CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-{{(1R,4S)-1-butyl-4-{8-[ (4-methoxybenzyl)oxy]butyl}octyl-2-yne-1,4-diyl}bis(oxy)}bis[(tert-butyl)dimethylsilane](1323140-48-2)
• EPA Substance Registry System: 1,1'-{{(1R,4S)-1-butyl-4-{8-[ (4-methoxybenzyl)oxy]butyl}octyl-2-yne-1,4-diyl}bis(oxy)}bis[(tert-butyl)dimethylsilane](1323140-48-2)

Safety Data

• Hazardous Substances Data: 1323140-48-2(Hazardous Substances Data)

Upstream product

• 1323140-45-9 (8R)-8-{[ (tert-butyl)dimethylsilyl]oxy}-1-[(4-methoxybenzyl)oxy]dodec-6-yn-5-ol 
• 1323140-38-0 (8R)-8-{[ (tert-butyl)dimethylsilyl]oxy}-1-[(4-methoxybenzyl)oxy]dodec-6-yn-5-one 
• 1323140-54-0 (5R,8S)-5-{[ (tert-butyl)dimethylsilyl]oxy}-16-[(4-methoxybenzyl)oxy]hexadec-6-yn-5-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 33467-76-4 (E)-hept-2-en-1-ol 
• 1002-36-4 hep-2-yn-1-ol 
• 51703-65-2 (R)-1-heptyn-3-ol 
• 104528-17-8 (2R,3R)-(3-butyloxiranyl)methyl alcohol 
• 503088-34-4 (tert-butyl){[(1R)-1-butylprop-2-yn-1-yl]oxy}dimethylsilane 

Relevant articles and documents

First stereoselective total synthesis of gallicynoic acids G and H

A stereoselective convergent total synthesis of two acetylenic acids, gallicynoic acid G (1) and H (2), is reported, involving asymmetric reduction of alkynones 3 and 4, respectively, with the Corey- Bakshi-Sibata (CBS) catalyst as a key step (Scheme 3), 3 and 4 being obtained from a common intermediate, the chiral alkynol 12 (Scheme 2). Copyright