1314-80-3 Usage
Description
Phosphorus pentasulfide, also known as phosphoric sulfide (P2S5), is a nonmetallic inorganic compound that appears as a yellow to greenish-yellow crystalline mass with an odor similar to hydrogen sulfide. It is a dangerous fire risk, igniting by friction or in contact with water, and decomposes upon contact with water or moist air, releasing toxic and flammable hydrogen sulfide gas. With a boiling point of 995°F (535°C) and an ignition temperature of 287°F (141°C), it has a specific gravity of 2.09, making it heavier than water. It is toxic by inhalation, with a TLV of 1 mg/m3 of air, and has a four-digit UN identification number of 1340. The NFPA 704 designation for phosphorus pentasulfide is health 2, flammability 1, and reactivity 2.
Uses
Used in Chemical Industry:
Phosphorus pentasulfide is used as a reagent for introducing sulfur into organic compounds, playing a crucial role in the synthesis of various sulfur-containing organic molecules.
Used in Pesticide Industry:
Phosphorus pentasulfide is used as an insecticide, helping to control and eliminate pests in agricultural and other settings.
Used in Lubricant Industry:
Phosphorus pentasulfide is used as an additive in the manufacture of lubricant additives, enhancing the performance and properties of lubricants.
Used in Safety Matches Industry:
Phosphorus pentasulfide is used as a component in the production of safety matches, providing the necessary chemical reaction for ignition.
Used in Flotation Industry:
Phosphorus pentasulfide is used as a flotation agent in the mining and mineral processing industries, aiding in the separation of valuable minerals from waste materials.
Used in Asphalt Industry:
Phosphorus pentasulfide is used in the production of blown asphalt, a type of modified asphalt that has improved properties for use in road construction and other applications.
Air & Water Reactions
Highly flammable. May heat and spontaneously ignite in presence of moisture [Haz. Chem. Data. 1969]. Reaction with water forms toxic hydrogen sulfide gas and phosphoric acid. Dangerous when wet.
Reactivity Profile
PHOSPHORUS PENTASULFIDE reacts vigorously with strong oxidants. Exothermically violent decomposition reaction with water, steam or acids to produce irritating fumes of phosphorus pentaoxide and highly toxic hydrogen sulfide gas. May ignite in contact with limited amounts of water [Haz. Chem. Data, 1975, p. 239]. Can be ignited by sparks or friction and its dust presents an explosion hazard in air at sufficient concentrations. Hydrogen sulfide gas evolved from reactions with water may also form explosive mixtures with air.
Health Hazard
Phosphorus pentasulfide is an irritant to the skin and eyes. Inhalation of its vapors can cause irritation of the respiratory passage. Oral toxicity of this compound in rats was found to be moderate.LD50 value, oral (rats): 389 mg/kg (NIOSH 1986)Phosphorus pentasulfide can readily produce highly toxic hydrogen sulfide in the presence of moisture. Other toxic products from its combustion are sulfur dioxide and phosphorus pentoxide (corrosive)..
Fire Hazard
Special Hazards of Combustion Products: Products of combustion include sulfur dioxide and phosphorus pentoxide, which are irritating, toxic and corrosive.
Flammability and Explosibility
Highlyflammable
Safety Profile
A poison by ingestion.
A severe eye and skin irritant. Readily
liberates toxic hydrogen sulfide and
phosphorus pentoxide and evolves heat on
contact with moisture. Dangerous fire
hazard in the form of dust when exposed to
heat or flame. Spontaneous heating in the
presence of moisture. Moderate explosion
hazard in solid form by spontaneous
chemical reaction. Reacts with water, steam,
or acids to produce toxic and flammable
vapors; can react vigorously with oxidizing
materials. Incompatible with air, alcohols,
water. To fight fire, use CO2snow, dry
chemical, or sand. Used as an intermedate
in manufacturing lubricant addltives,
insecticides, and fertilizer agents. When
heated to decomposition it emits highly
toxic fumes of SO, and PO,. See also
HYDROGEN SULFIDE.
Potential Exposure
Phosphorus pentasulfide is used as an intermediate in the manufacture of lubricant additives; insecticides, flotation agents; lubricating oil; ignition compounds; and matches. It is also used to introduce sulfur into rubber, and organic chemicals, such as pharmaceuticals.
Shipping
UN1340 Phosphorus pentasulfate, free from yellow or white phosphorus, Hazard Class: 4.3; Labels: 4.3-Dangerous when wet material, 4.1-flammable solid.
Purification Methods
Purify P2S5 by extraction and crystallisation with CS2, using a Soxhlet extractor, and is heated in a CO2 atmosphere at 150o to remove solvent. It liberates H2S in moist air. HARMFUL VAPOURS. [Klements in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 568 1963.]
Incompatibilities
Flammable solid; dust may form explosive mixture with air. Contact with water forms phosphorus pentoxide and an explosive mixture of hydrogen sulfide with air. Phosphorus pentasulfide is incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, ammonia, strong acids, strong bases, alcohols. Reaction with water or moisture in the air releases heat, hydrogen sulfide (H2S), sulfur dioxide, and phosphoric acid. Pyrophoric hazard, may self-ignite in moist air.
Waste Disposal
Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Decompose with water, forming phosphoric acid, sulfuric acid and hydrogen sulfide. Provisions must be made for scrubbing hydrogen sulfide emissions. The acids may then be neutralized and diluted slowly to solution of soda ash and slaked lime with stirring, then flush to sewer with large volumes of water.
Check Digit Verification of cas no
The CAS Registry Mumber 1314-80-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,3,1 and 4 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1314-80:
(6*1)+(5*3)+(4*1)+(3*4)+(2*8)+(1*0)=53
53 % 10 = 3
So 1314-80-3 is a valid CAS Registry Number.
InChI:InChI=1/H4O5P2S2/c1-6(2,8)5-7(3,4)9/h(H2,1,2,8)(H2,3,4,9)
