130249-22-8Relevant articles and documents
1,2-Functionalization of α,β-Epoxycycloalkanones
Kang, Jahyo,Kim, Do Hyung,Lee, Jae Hyoung,Rim, Jong Gil,Yoon, Yu Bong,Kim, Kyungjin
, p. 5555 - 5558 (2007/10/02)
For 1,2-functionalization, α,β-epoxy cycloalkanones were treated with 2.1 equiv of 2-lithio-2-(trimethylsilyl)-1,3-dithiane to give high yields of trans-2-dithianyl-3-dithianylidene-1-cycloalkanols, which were oxidatively hydrolyzed with an excess of halogenating agents in alcohols to the corresponding acetal esters.