129970-93-0Relevant articles and documents
Enzymatic Synthesis of a Series of Thioglycosides: Analogs of Arbutin with Efficient Antipigmentation Properties
Daniellou, Richard,Didak, Blanka,Guillotin, Laure,Lafite, Pierre,Landemarre, Ludovic,Lemiègre, Lo?c,Peyrot, Cédric
, p. 3812 - 3818 (2021)
Arbutin, a natural glycoside, is well known as a commercial tyrosinase inhibitor, and thus, to prevent pigmentary disorders of skin. In fact, tyrosinase is involved in the biosynthesis of melanin, the skin main pigment. However, arbutin is subject to hydr
Protecting-group-free synthesis of glycopolymers bearing thioglycosides via one-pot monomer synthesis from free saccharides
Tanaka, Tomonari,Inoue, Genri,Shoda, Shin-Ichiro,Kimura, Yoshiharu
, p. 3513 - 3520 (2016/02/18)
Polyacrylamides having pendant thioglycosides were successfully synthesized from thioglycosidic monomers that were readily prepared by one-pot method without any protection of the hydroxy groups on the starting free saccharides. The glycomonomers were synthesized by the direct synthesis of thioglycosides using 2-chloro-1,3-dimethylimidazolinium chloride and 4-aminobenzentiol, and the following acrylamidation. They were co-polymerized with acrylamide into glycopolymers by reversible addition-fragmentation chain transfer polymerization using a trithiocarbonate derivative as a chain transfer agent. The gold nanoparticles and gold-coated quartz crystal microbalance sensor immobilized with the thiol-terminated glycopolymers exhibited high affinity for the corresponding lectins due to multivalent interaction between saccharides and protein in aqueous solution.
Substituted phenyl-1-thio(poly-O-sulfo)-α(or β)-D-glucopyranosides
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, (2008/06/13)
Cation salts of substituted phenyl-1-thio(poly-O-sulfo)-α(or β)-D-glucopyranoside, useful as modulators of the complement system, the intermediates thereof and the process of making such intermediates and end products.
