128752-86-3

Basic information

• Product Name: diethyl <2-(p-methylphenyl)ethyl>malonate
• CAS NO: 128752-86-3
• Molecular Weight: 278.348
• Mol File: 128752-86-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: diethyl <2-(p-methylphenyl)ethyl>malonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl <2-(p-methylphenyl)ethyl>malonate(128752-86-3)
• EPA Substance Registry System: diethyl <2-(p-methylphenyl)ethyl>malonate(128752-86-3)

Safety Data

• Hazardous Substances Data: 128752-86-3(Hazardous Substances Data)

Upstream product

• 996-82-7 sodium diethylmalonate 
• 6529-51-7 2-(4-methylphenyl)ethyl bromide 
• 14064-10-9 diethyl 2-chloromalonate 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 105-53-3 diethyl malonate 
• 72174-95-9 diethyl 2-(4-methylphenyl)cyclopropane-1,1-dicarboxylate 

Relevant articles and documents

Direct Copper-Catalyzed C-H Monofluoroalkylation of Benzoxazoles with 1-Fluoro-1-haloalkanes

The first example of direct C–H bond monofluoroalkylation with 1-fluoro-1-haloalkanes with no adjacent functional groups and with β-hydrogens has been developed. This transformation offers a straightforward route for the synthesis of a series of monofluoroalkylated benzoxazoles.

Relative Rates for the Addition Reactions of the Malonyl Radical to Substituted Styrenes Induced by Cerium(IV) Ammonium Nitrate and Tributyltin Hydride. A Comparison

The relative rates for the addition reactions of the malonyl radical to substituted styrenes induced by cerium(IV) ammonium nitrate (CAN) and tributyltin hydride have been determined.The two processes exhibit practically identical ρ+ values (-1.05 and -1.06), thus suggesting that the coordination between the metal and the radical does not play a significant role in the CAN-promoted oxidative additions.