128337-03-1Relevant articles and documents
On the Mechanism of Carbon-Hydrogen Activation in Gif-type Reactions. Kinetic Isotopic Effects in Pyridine Solution.
Barton, Derek H. R.,Doller, Dario,Geletii, Yurii V.
, p. 3811 - 3814 (1991)
Kinetic isotopic effects (KIE) were measured for oxidation, bromination and selenylation of c-C6H12/c-C6D12 in pyridine solution for different Gif-type, Fenton and other systems.The comparison of KIE and relative reactivity data for the pair c-C5H10/c-C6H12 proved that the mechanism of activation in Gif-type reactions is different from a hydrogen atom abstraction.