1266145-47-4Relevant articles and documents
Direct and enantioselective a-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis
Mastracchio, Anthony,Warkentin, Alexander A.,Walji, Abbas M.,MacMillan, David W. C.
experimental part, p. 20648 - 20651 (2011/09/16)
The first enantioselective organocatalytic a-allylation of cyclic ketones has been accomplished via singly occupied molecular orbital catalysis. Geometrically constrained radical cations, forged from the one-electron oxidation of transiently generated ena