125685-29-2

Basic information

• Product Name: (R)-2-[(R)-(tert-Butyl-dimethyl-silanyloxy)-phenyl-methyl]-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-hexan-1-one
• Synonyms: (R)-2-[(R)-(tert-Butyl-dimethyl-silanyloxy)-phenyl-methyl]-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-hexan-1-one
• CAS NO: 125685-29-2
• Molecular Weight: 533.848
• Mol File: 125685-29-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-[(R)-(tert-Butyl-dimethyl-silanyloxy)-phenyl-methyl]-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-hexan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-[(R)-(tert-Butyl-dimethyl-silanyloxy)-phenyl-methyl]-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-hexan-1-one(125685-29-2)
• EPA Substance Registry System: (R)-2-[(R)-(tert-Butyl-dimethyl-silanyloxy)-phenyl-methyl]-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-hexan-1-one(125685-29-2)

Safety Data

• Hazardous Substances Data: 125685-29-2(Hazardous Substances Data)

Upstream product

• 142-61-0 Hexanoyl chloride 
• 125664-99-5 N-<(2R,3S)-3-hydroxy-2-methylbutanoyl>bornane-10,2-sultam 
• 125664-97-3 1-((3aS,6R,7aR)-8,8-dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)hexan-1-one 
• 125664-96-2 N-butanoylbornane-10,2-sultam 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 125665-07-8 N-<(2R,3R)-2-(hydroxybenzyl)hexanoyl>bornane-10,2-sultam 
• 94594-90-8 (2R)-bornane-10,2-sultam 
• 100-52-7 benzaldehyde 
• 125665-04-5 N-<(2S,3S)-2-(hydroxybenzyl)butanoyl>bornane-10,2-sultam 
• 125665-04-5 N-<(2R,3R)-2-(hydroxybenzyl)butanoyl>bornane-10,2-sultam 
• 125760-63-6 N-<(2S,3R)-2-methyl-3-hydroxy-3-phenylpropanoyl>bornane-10,2-sultam 
• 125664-98-4 (2R,3R)-1-((6R)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-3-hydroxy-2-methyl-3-phenylpropan-1-one 
• 125665-09-0 N-<(2S,3R)-2-ethyl-3-hydroxy-(E)-hexenoyl>bornane-10,2-sultam 
• 125665-02-3 N-<(2S,3R)-2-methyl-3-hydroxy-(E)-4-hexenoyl>bornane-10,2-sultam 

Relevant articles and documents

Bornanesultam-directed asymmetric synthesis of crystalline, enantiomerically pure syn aldols

N-acylsultams 2 furnish, via aldolization of their enolates 16 with aldehydes, diastereomerically pure, crystalline syn aldols. The absolute configuration of the product is controlled by the choice of the enolate counterion: 16, M = B → 3; 16, M = Li or S