124603-53-8

Basic information

• Product Name: (5S)-(+)-5-isopropenyl-2-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene
• Synonyms: (5S)-(+)-5-isopropenyl-2-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene
• CAS NO: 124603-53-8
• Molecular Weight: 308.58
• Mol File: 124603-53-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (5S)-(+)-5-isopropenyl-2-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (5S)-(+)-5-isopropenyl-2-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene(124603-53-8)
• EPA Substance Registry System: (5S)-(+)-5-isopropenyl-2-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene(124603-53-8)

Safety Data

• Hazardous Substances Data: 124603-53-8(Hazardous Substances Data)

Upstream product

• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 201012-68-2 (5S)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-one 

Downstream Products

• 172605-71-9 E-(5R,6S)-5-isopropyl-6-amino-2-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene 
• 172605-69-5 (+)-(5R,6S)-5-isopropyl-6-(4-methylphenylsulfonyl)amino-2-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene 
• 172605-68-4 (5S)-(+)-5-isopropyl-2-methyl-1-triisopropylsilyl(oxy)-cyclohex-1-ene 
• 124603-54-9 N-((1S,6R)-6-Isopropenyl-3-methyl-2-triisopropylsilanyloxy-cyclohex-2-enyl)-4-methyl-benzenesulfonamide 

Relevant articles and documents

New Trialkylsilyl Enol Ether Chemistry: α-N-Tosylamination of Triisopropylsilyl Enol Ethers

Triisopropylsilyl enol ethers react with (TsN)2Se to give α-N-tosylamino derivatives in modest to good yields.In the absence of 1,3-diaxial interactions the N-tosylamino group prefers an axial conformation.The axial N-tosylamino derivatives can be readily transformed into the azabicyclononane skeleton, the core structure of a number of alkaloids.