12246-51-4 Usage
Description
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER is a yellow solid that is a type of organoiridium compound. It is known for its catalytic properties in various chemical reactions, making it a valuable component in the field of chemistry and materials science.
Uses
Used in Chemical Synthesis:
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER is used as a catalyst for isomerization-hydroboration reactions with nido-carboranyldiphosphine as a stabilizing ligand. This application is crucial for the selective synthesis of complex organic molecules.
Used in Oxidation Reactions:
In the field of organic chemistry, BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER is used as a catalyst for the hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions. This process is essential for the synthesis of various pharmaceutical compounds and natural products.
Used in Solid-Phase Synthesis:
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER is employed as a catalyst for the immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions. This application is vital in the development of new materials and the synthesis of complex organic compounds on solid supports.
Used in Alkylation Reactions:
In the petrochemical industry, BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER is used as a catalyst for alkylation reactions, which are crucial for producing high-octane gasoline and other valuable chemicals.
Used in the Guerbet Reaction:
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER is utilized as a catalyst in the Guerbet reaction, a process that converts primary alcohols into higher alcohols and alkanes. This reaction is significant in the production of chemicals used in the synthesis of detergents, lubricants, and surfactants.
Used in Allylic Amination Reactions:
In the pharmaceutical industry, BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER is used as a catalyst for allylic amination reactions in a DNA-diene-iridium(I) hybrid system. This application is essential for the synthesis of various pharmaceutical compounds, including those with potential anti-cancer properties.
Used in Asymmetric Hydroamination Reactions:
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER is also used as a catalyst in asymmetric hydroamination reactions, which are important for the enantioselective synthesis of chiral amines. These reactions are crucial in the production of pharmaceuticals, agrochemicals, and other specialty chemicals.
Check Digit Verification of cas no
The CAS Registry Mumber 12246-51-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,2,2,4 and 6 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 12246-51:
(7*1)+(6*2)+(5*2)+(4*4)+(3*6)+(2*5)+(1*1)=74
74 % 10 = 4
So 12246-51-4 is a valid CAS Registry Number.
InChI:InChI=1/4C8H14.4CH3.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;;;;;/h4*1-2H,3-8H2;4*1H3;2*1H;;/b4*2-1-;;;;;;;;/r4C8H14.C4H14Cl2Ir2/c4*1-2-4-6-8-7-5-3-1;1-7(2)5-8(3,4)6-7/h4*1-2H,3-8H2;5-6H,1-4H3/b4*2-1-;
12246-51-4Relevant articles and documents
Electron-rich Vaska-type complexes trans-[Ir(CO)Cl(2-Ph2PC 6H4COOMe)2] and trans-[Ir(CO)Cl(2-Ph 2PC6H4OMe)2]: Synthesis, characterisation and reactivity
Dutta, Dipak Kumar,Deb, Biswajit,Sarmah, Bhaskar Jyoti,Woollins, J. Derek,Slawin, Alexandra M. Z.,Fuller, Amy L.,Randall, Rebecca A. M.
, p. 835 - 841 (2011/05/13)
The in-situ-generated dimeric precursor [Ir(CO)2Cl]2 reacts with four molar equivalents of the ligands 2-Ph2PC 6H4COOMe (a) and 2-Ph2PC6H 4OMe (b) to afford tetracoord
