120109-26-4

Basic information

• Product Name: butyl 3-methylthio-2-(1-phenylethylamino)-4-pentenoate
• CAS NO: 120109-26-4
• Molecular Weight: 321.484
• Mol File: 120109-26-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: butyl 3-methylthio-2-(1-phenylethylamino)-4-pentenoate(CAS DataBase Reference)
• NIST Chemistry Reference: butyl 3-methylthio-2-(1-phenylethylamino)-4-pentenoate(120109-26-4)
• EPA Substance Registry System: butyl 3-methylthio-2-(1-phenylethylamino)-4-pentenoate(120109-26-4)

Safety Data

• Hazardous Substances Data: 120109-26-4(Hazardous Substances Data)

Upstream product

• 10152-76-8 allylmethyl sulfide 
• 100018-34-6 n-butyl N-((1S)-phenylethyl)-α-iminoacetate 

Relevant articles and documents

STUDIES ON THE REACTION OF α-IMINO ESTERS WITH ORGANOMETALLIC COMPOUNDS

Benzylzinc reagent reacted with α-amino ester ( 2 ) at the α-carbon exclusively, though other organometallic reagents such as Mg, Al, Cu, Ti, and B derivatives reacted at the nitrogen atom.Use of the (S)-amine as a chiral auxiliary of 2 created the R chirality at the imino carbon.Very high chiral induction was realized in the reaction of prenylzinc reagent with α-imino 8-(-)phenylmenthyl ester ( 10 ).The reaction of 2 with heteroatom substituted allylic organometallic compounds ( 15 ) gave the corresponding α-heteroatom substituted amino acid derivatives ( 16 ).Here again, the allylic zinc reagent gave the adduct in higher yield than the corresponding Ti, Al, and B reagents.