1173163-89-7Relevant articles and documents
Transition-metal-catalyzed regioselective aroyl- and trifluoro- acetylthiolation of alkynes using thioesters
Minami, Yasunori,Kuniyasu, Hitoshi,Miyafuji, Kiyoshi,Kambe, Nobuaki
supporting information; experimental part, p. 3080 - 3082 (2009/12/01)
Intermolecular CO-retained carbothiolation of alkynes using thioesters took place to afford β-SR substituted enone derivatives; the choice of catalyst (Pd(dba)2-dppe) and the introduction of a CF3 group into the thioesters are the key to achieving the transformation. The Royal Society of Chemistry 2009.