114925-52-9

Basic information

• Product Name: <4R-(4α,5α)>-4-<(phenylmethoxy)methyl>-6-ethenyl-2,2-dimethyl-1,3-dioxane
• Synonyms: <4R-(4α,5α)>-4-<(phenylmethoxy)methyl>-6-ethenyl-2,2-dimethyl-1,3-dioxane
• CAS NO: 114925-52-9
• Molecular Weight: 262.349
• Mol File: 114925-52-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: <4R-(4α,5α)>-4-<(phenylmethoxy)methyl>-6-ethenyl-2,2-dimethyl-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: <4R-(4α,5α)>-4-<(phenylmethoxy)methyl>-6-ethenyl-2,2-dimethyl-1,3-dioxane(114925-52-9)
• EPA Substance Registry System: <4R-(4α,5α)>-4-<(phenylmethoxy)methyl>-6-ethenyl-2,2-dimethyl-1,3-dioxane(114925-52-9)

Safety Data

• Hazardous Substances Data: 114925-52-9(Hazardous Substances Data)

Upstream product

• 142176-75-8 (Z)-(R)-1-benzyloxy-6-(trimethyl-silanyl)-hex-4-en-2-ol 
• 142176-95-2 (R)-1-Benzyloxy-6-trimethylsilanyl-hex-4-yn-2-ol 
• 14618-80-5 (R)-benzyl glycidol 
• 114861-37-9 3-deoxy-5-O-(phenylmethyl)-α-L-xylofuranose 
• 114861-24-4 3-deoxy-1,2-O-(1-methylethylidene)-5-O-(phenylmethyl)-α-L-xylofuranose 
• 114861-23-3 3-deoxy-1,2-O-isopropylidene-α-L-erythro-pentofuranose 
• 41546-31-0 L-xylose 
• 100-39-0 benzyl bromide 
• 106799-17-1 (2R,4S)-1-<(phenylmethoxy)methyl>5-hexene-2,4-diol 
• 77-76-9 2,2-dimethoxy-propane 
• 106799-17-1 (2R)-1-(benzyloxy)-5-hexene-2,4-diol 
• 114861-22-2 1,2-O-isopropylidene-α-L-xylofuranose 
• 114861-15-3 Thiocarbonic acid O-[(3aS,5S,6R,6aS)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl] ester O-phenyl ester 
• 220827-73-6 5-O-tert-butyldiphenylsilyl-1,2-O-isopropylidene-α-L-xylofuranose 

Downstream Products

• 106799-18-2 3,5-dideoxy-6-O-<(1,1-dimethylethyl)dimethylsilyl>-2,4-O-(1-methylethylidene)-1-O-(phenylmethyl)-D-erythro-hexitol 
• 114925-53-0 3,5-dideoxy-2,4-O-(1-methylethylidene)-1-O-(phenylmethyl)-D-erythro-hexitol 
• 112497-21-9 (4S,6S)-6-<(benzyloxy)methyl>-4-(2-hydroxyethyl)-2,2-dimethyl-1,3-dioxacyclohexane 

Relevant articles and documents

Stereoselective synthesis of syn1,3-diols

Z-allylsilanes 1 are epoxidized by V5+/TBHP with high erythro-selectivity (up to 97:3). HF- or TBAFinduced fragmentation leads to syn-l,3-diols 3. Compound 3f can be gtransformed within two steps into a key synthon for the lactone moiety of com

Stereocontrolled Construction of Key Building Blocks for the Total Synthesis of Amphoteronolide B and Amphotericin B

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