1123-56-4Relevant articles and documents
Zhi, Jian,Mitchell, Sharon,Pérez-Ramírez, Javier,Reiser, Oliver
, p. 2585 - 2589 (2015)
Electrochromism of fast photochromic radical complexes forming light-unresponsive stable colored radical cation
Yamamoto, Katsuya,Gomita, Isshu,Okajima, Hajime,Sakamoto, Akira,Mutoh, Katsuya,Abe, Jiro
, p. 4917 - 4920 (2019)
We demonstrated the electrochromism of photochromic radical complexes containing triaryl imidazole: fast photoswitchable pentaarylbiimidazole (PABI) and the phenoxyl-imidazolyl radical complex (PIC). Cyclic voltammetry and spectroelectrochemistry revealed
Diels-Alder Cycloaddition of C60 with Photochemically Generated Hydroxy to o-quinodimethanes Governed by Steric Factors: A Mechanistic Study
Roubelakis, Manolis M.,Malliaros, Nikitas G.,Orfanopoulos, Michael
, p. 5694 - 5703 (2019)
Photoexcited o-alkyl-substituted benzaldehydes add to C60through their photoenol reactive intermediates producing stable [4 + 2] fullerene adducts. A mechanistic approach for this reactivity of C60 is provided, based mainly on intra-
PROCESS FOR PREPARING 2,6-DIALKYLPHENYLACETIC ACIDS
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Paragraph 0216-0219, (2022/01/04)
The invention relates to a multi-stage process for preparing 2,6-dialkylphenylacetic acids of the general formula (I) by reacting 2,6-dialkylbromobenzenes with (1) magnesium, (2) a formamide, (3) an acid, (4) hydrogenation of the benzaldehyde obtained, (5
Palladium-Catalyzed Reductive Carbonylation of (Hetero) Aryl Halides and Triflates Using Cobalt Carbonyl as CO Source
Dogga, Bhushanarao,Joseph, Jayan T.,Kumar, C. S. Ananda
supporting information, p. 309 - 313 (2020/12/23)
An efficient protocol for the reductive carbonylation of (hetero) aryl halides and triflates under CO gas-free conditions using Pd/Co2(CO)8 and triethylsilane has been developed. The mild reaction conditions, enhanced chemoselectivity and, easy access to heterocyclic and vinyl carboxaldehydes highlights its importance in organic synthesis.
Palladium-catalysed annulative allylic alkylation for the synthesis of benzannulated heteroarenes
Yadav, Sonu,Ramasastry
supporting information, p. 77 - 80 (2021/01/13)
A conceptually novel intramolecular allylic alkylation strategy is developed for the synthesis of carbazoles and dibenzothiophenes. In an unusual event, palladium catalyses the formation of π-allylpalladium complexes of the respective (2-methylindol-3-yl)allyl acetates and subsequently facilitates the benzannulation process. This journal is