1123-40-6 Usage
Description
3,3-Dimethylglutarimide, also known as 3,3'-dimethylglutarimide, is a white to white-grey crystalline powder with chemical properties that make it a versatile compound in various applications. It is known for its ability to form heterodimers and has been used as a substitute for barbital in certain contexts.
Uses
Used in Pharmaceutical Industry:
3,3-Dimethylglutarimide is used as a barbital substitute for its ability to mimic the properties of barbital in pharmaceutical formulations. This substitution can lead to improved safety profiles and reduced side effects compared to traditional barbital-based compounds.
Used in Chemical Synthesis:
3,3-Dimethylglutarimide is used as a key intermediate in the synthesis of various organic compounds, particularly in the formation of heterodimers. Its unique chemical structure allows for the creation of novel molecules with potential applications in various industries, including pharmaceuticals, agrochemicals, and materials science.
Used in Research and Development:
3,3-Dimethylglutarimide is utilized in research and development settings to explore its potential applications and properties. Its ability to form heterodimers and act as a barbital substitute makes it an interesting compound for scientists to study and develop new applications and products.
Purification Methods
Recrystallise the imide from hot H2O or EtOH [Arnett & Harrelson J Am Chem Soc 109 809 1987]. [Beilstein 21 H 391, 21 I 331, 21 II 309, 21 III/IV 4601, 21/9 V 592.]
Check Digit Verification of cas no
The CAS Registry Mumber 1123-40-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,2 and 3 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1123-40:
(6*1)+(5*1)+(4*2)+(3*3)+(2*4)+(1*0)=36
36 % 10 = 6
So 1123-40-6 is a valid CAS Registry Number.
InChI:InChI=1/C7H11NO2/c1-7(2)3-5(9)8-6(10)4-7/h3-4H2,1-2H3,(H,8,9,10)
1123-40-6Relevant articles and documents
Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly
Young, Michael C.,Liew, Erica,Ashby, Jonathan,McCoy, Kelsi E.,Hooley, Richard J.
, p. 6331 - 6333 (2013)
Iron complexes derived from 6-diaminotriazyl-2,2′-bipyridines display spin crossover behaviour, and hydrogen bonding-controlled self-assembly with a suitable barbiturate partner can modulate the crossover from mixed low and high spin to high spin. This system is the first to use solution-phase self-assembly of complementary hydrogen-bonding organic species to modulate spin state.
Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly
Young, Michael C.,Liew, Erica,Ashby, Jonathan,McCoy, Kelsi E.,Hooley, Richard J.
supporting information, p. 6331 - 6333 (2013/08/23)
Iron complexes derived from 6-diaminotriazyl-2,2′-bipyridines display spin crossover behaviour, and hydrogen bonding-controlled self-assembly with a suitable barbiturate partner can modulate the crossover from mixed low and high spin to high spin. This system is the first to use solution-phase self-assembly of complementary hydrogen-bonding organic species to modulate spin state.
SYNTHESIS AND PROPERTIES OF 4,4-DIMETHYLCONIINE DERIVATIVES
Chabudzinski, Zenon,Czuba, Wladyslaw,Lipnicka, Urszula,Rykowski, Zbigniew,Sedzik-Hibner, Dorota,Wrzesien, Justyna
, p. 1459 - 1463 (2007/10/02)
In the course of transformations of 4,4-dimethyl-6-acetonylpiperid-2-one, a series of 4,4-dimethylconiine derivatives exhibiting an influence on the arterial blood-pressure was synthesized.The structure of new compounds was established on the basis of spectral data and chemical reactions leading finally to known 4,4-dimethylpiperid-2,6-dione.
