1119301-53-9Relevant articles and documents
Evolution of the total synthesis of (-)-Okilactomycin exploiting a tandem oxy-cope rearrangement/oxidation, a petasis-ferrier union/rearrangement, and ring-closing metathesis
Smith, Amos B. III,Bosanac, Todd,Basu, Kallol
supporting information; experimental part, p. 2348 - 2358 (2009/07/30)
An effective, asymmetric total synthesis of the antitumor antibiotic (-)-okilactomycin (1), as well as assignment of the absolute configuration,has been achieved exploiting a convergent strategy. Highlights of the s ynthesis include a diastereoselective o
