106256-92-2

Basic information

• Product Name: methyl 2,3-di-O-acetyl-4-O-trideuterioacetyl-6-O-trityl-α-D-glucopyranoside
• CAS NO: 106256-92-2
• Molecular Weight: 565.593
• Mol File: 106256-92-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-acetyl-4-O-trideuterioacetyl-6-O-trityl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-acetyl-4-O-trideuterioacetyl-6-O-trityl-α-D-glucopyranoside(106256-92-2)
• EPA Substance Registry System: methyl 2,3-di-O-acetyl-4-O-trideuterioacetyl-6-O-trityl-α-D-glucopyranoside(106256-92-2)

Safety Data

• Hazardous Substances Data: 106256-92-2(Hazardous Substances Data)

Upstream product

• 16649-49-3 Acetic anhydride-d6 
• 76-83-5 trityl chloride 
• 29868-42-6 methyl 2,3-di-O-acetyl-α-D-glucopyranoside 

Relevant articles and documents

ROTATIONAL ISOMERISM ABOUT THE C-5-C-6 BOND OF 6-O-TRITYL DERIVATIVES OF ALDOHEXOPYRANOSES, AND OF ANALOGS OF D-GALACTOPYRANOSE MODIFIED AT C-4

Differences in rotational isomerism about the C-5-C-6 bond of 4-O-acetyl-6-O-tritylaldohexopyranose derivatives in the gluco and manno, as compared with the galacto, series are reflected in different contributions towards diamagnetic shielding of the acetoxyl protons, and rotatory characteristics of the compounds.Among 4-deoxy-4-halogeno analogs of methyl β-D-galactopyranoside, rotational isomerism varies little, based on H-5,6,6' coupling, whereas the 6,6'-protons exhibit enhanced anisochronism as the mass of the halogen atom increases.The identification of resonance signals due to H-6R and H-6S, respectively, provides a basis for the consideration of these findings.