105460-59-1 Usage
Description
4-tert-ButyldiMethylsilyloxybenzeneacetic Acid Methyl Ester is an organic compound that serves as a crucial intermediate in the synthesis of various fine chemicals. It is characterized by its clear oil appearance and possesses unique chemical properties that make it valuable in the development of new applications.
Uses
Used in Pharmaceutical Industry:
4-tert-ButyldiMethylsilyloxybenzeneacetic Acid Methyl Ester is used as a key intermediate for the synthesis of pharmaceutical compounds. Its unique structure allows for the development of new drugs with potential therapeutic applications.
Used in Chemical Synthesis:
In the field of chemical synthesis, 4-tert-ButyldiMethylsilyloxybenzeneacetic Acid Methyl Ester is utilized as a versatile building block for creating a wide range of fine chemicals. Its reactivity and functional groups enable the production of various compounds with diverse applications.
Used in Research and Development:
4-tert-ButyldiMethylsilyloxybenzeneacetic Acid Methyl Ester is also employed in research and development settings, where it is used to explore new chemical reactions and develop innovative synthetic methods. Its unique properties make it an attractive candidate for further investigation and potential commercialization.
Used in Material Science:
In the material science field, 4-tert-ButyldiMethylsilyloxybenzeneacetic Acid Methyl Ester may be used as a component in the development of new materials with specific properties, such as improved stability or enhanced reactivity.
Used in Agricultural Industry:
4-tert-ButyldiMethylsilyloxybenzeneacetic Acid Methyl Ester can be used as an intermediate in the synthesis of agrochemicals, contributing to the development of new pesticides or other agricultural products.
Used in Flavor and Fragrance Industry:
Due to its unique chemical structure, 4-tert-ButyldiMethylsilyloxybenzeneacetic Acid Methyl Ester may also find applications in the flavor and fragrance industry, where it can be used to create new and distinct scents or flavors for various products.
Check Digit Verification of cas no
The CAS Registry Mumber 105460-59-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,5,4,6 and 0 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 105460-59:
(8*1)+(7*0)+(6*5)+(5*4)+(4*6)+(3*0)+(2*5)+(1*9)=101
101 % 10 = 1
So 105460-59-1 is a valid CAS Registry Number.
105460-59-1Relevant articles and documents
A deprotection procedure using SO3H silica gel to remove non-silyl protecting groups
Karaki, Fumika,Kuwada, Miki,Tajiri, Saki,Kanda, Misaki,Yanai, Mari,Kamimura, Mitsuhiro,Itoh, Kennosuke,Fujii, Hideaki
supporting information, p. 212 - 220 (2019/05/06)
Protecting groups are indispensable in organic synthesis and there is a great need for a variety of deprotection methods. Here, we investigated the scope of the application of a deprotection procedure using SO3H silica gel, which we have previously reported as a desilylation procedure. Under these conditions, -OMOM, -OSEM, -OTHP, and -OAc groups and dimethyl acetal were cleaved. Pivaloyloxy, benzyloxy and methoxy carbonyl groups remained intact and selective deprotection of TBS groups in the presence of other protecting groups was accomplished. We succeeded in cleaving an acetyl group on a secondary alcohol in a highly polar nortropine derivative. Our findings here provide another deprotection option and would be helpful in the synthesis of multifunctional compounds.
Isomerization of olefins triggered by rhodium-catalyzed C-H bond activation: Control of endocyclic β-hydrogen elimination
Yip, Stephanie Y. Y.,A?ssa, Christophe
supporting information, p. 6870 - 6873 (2015/06/02)
Five-membered metallacycles are typically reluctant to undergo endocyclic β-hydrogen elimination. The rhodium-catalyzed isomerization of 4-pentenals into 3-pentenals occurs through this elementary step and cleavage of two C-H bonds, as supported by deuterium-labeling studies. The reaction proceeds without decarbonylation, leads to trans olefins exclusively, and tolerates other olefins normally prone to isomerization. Endocyclic β-hydrogen elimination can also be controlled in an enantiodivergent reaction on a racemic mixture.
Synthetic libraries of tyrosine-derived bacterial metabolites
Georgiades, Savvas N.,Clardy, Jon
supporting information; experimental part, p. 3117 - 3121 (2009/04/03)
The preparation of a collection of 131 small molecules, reminiscent of families of long chain N-acyl tyrosines, enamides and enol esters that have been isolated from heterologous expression of environmental DNA (eDNA) in Escherichia coli, is reported. The synthetic libraries of N-acyl tyrosines and their 3-keto counterparts were prepared via solid-phase routes, whereas the enamides and enol esters were synthesized in solution-phase.
