1028648-09-0

Basic information

• Product Name: 3,9-diphenyl-9H-carbazole
• Synonyms: 3,9-diphenyl-9H-carbazole
• CAS NO: 1028648-09-0
• Molecular Weight: 319.406
• Mol File: 1028648-09-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 3,9-diphenyl-9H-carbazole(CAS DataBase Reference)
• NIST Chemistry Reference: 3,9-diphenyl-9H-carbazole(1028648-09-0)
• EPA Substance Registry System: 3,9-diphenyl-9H-carbazole(1028648-09-0)

Safety Data

• Hazardous Substances Data: 1028648-09-0(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 1153-85-1 3-bromo-9-phenyl-9H-carbazole 
• 854952-58-2 N-phenyl-9H-carbazol-3-boronic acid 
• 100-63-0 phenylhydrazine 
• 1592-95-6 3-bromo-9H-carbazole 
• 103012-26-6 3-phenyl-9H-carbazole 
• 98-80-6 phenylboronic acid 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 3262-89-3 triphenylboroxine 
• 502161-03-7 3-iodo-9-phenyl-9H-carbazole 
• 591-50-4 iodobenzene 

Downstream Products

• 1133058-06-6 (6,9-diphenyl-9H-carbazol-3-yl)boronic acid 
• 1383628-18-9 C₃₆H₂₄N₂ 
• 1398395-80-6 C₄₂H₂₇BrN₂ 
• 1398395-86-2 C₄₂H₂₉BN₂O₂ 
• 1398395-57-7 C₅₆H₃₆N₄ 
• 1160294-85-8 3-bromo-N-phenyl-6-phenylcarbazole 

Relevant articles and documents

Concatenating Suzuki Arylation and Buchwald–Hartwig Amination by A Sequentially Pd-Catalyzed One-Pot Process—Consecutive Three-Component Synthesis of C,N-Diarylated Heterocycles

The concatenation of Suzuki coupling and Buchwald-Hartwig amination in a consecutive multicomponent reaction opens a concise, modular and efficient one-pot approach to diversely functionalized heterocycles, as exemplified for 3,10-diaryl 10H-phenothiazines, 3,9-diaryl 9H-carbazoles, and 1,5-diaryl 1H-indoles, in high yields starting from simple staring materials. Moreover, this one-pot reaction is a sequentially palladium-catalyzed process that does not require additional catalyst loading after the first coupling step.

Pd-NHCs Enabled Suzuki-Miyaura Cross-Coupling of Arylhydrazines via C–N Bond Cleavage

We describe a highly efficient protocol for cross-coupling of phenylhydrazines with arylboronic acids by Pd-NHCs under aerobic reaction condition. A series of well-defined Pd-NHCs complexes were evaluated and the relationship between the structure and the catalytic properties was investigated. It was disclosed that the Pd-PEPPSI-IPr proved to be the robust precatalyst, providing access to a range of (hetero)biaryls in good to excellent yields.

Bathocuproine-Enabled Nickel-Catalyzed Selective Ullmann Cross-Coupling of Two sp 2-Hybridized Organohalides

Cross-coupling reactions are essential for the synthesis of complex organic molecules. Here, we report a nickel-catalyzed Ullmann cross-coupling of two sp 2-hybridized organohalides, featuring high cross-selectivity when the two coupling partners are used in a 1:1 ratio. The high chemoselectivity is governed by the bathocuproine ligand. Moreover, the mild reductive reaction conditions allow that a wide range of functional groups are compatible in this Ullmann cross-coupling.