1026812-13-4

Basic information

• Product Name: 4-benzyloxy-3,5-dibromobenzyl bromide
• CAS NO: 1026812-13-4
• Molecular Weight: 434.953
• Mol File: 1026812-13-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-benzyloxy-3,5-dibromobenzyl bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-benzyloxy-3,5-dibromobenzyl bromide(1026812-13-4)
• EPA Substance Registry System: 4-benzyloxy-3,5-dibromobenzyl bromide(1026812-13-4)

Safety Data

• Hazardous Substances Data: 1026812-13-4(Hazardous Substances Data)

Upstream product

• 123-08-0 4-hydroxy-benzaldehyde 
• 2973-77-5 3,5-dibromo-4-hydroxybenzaldehyde 
• 100-39-0 benzyl bromide 
• 249515-06-8 4-(benzyloxy)-3,5-dibromobenzaldehyde 
• 249515-07-9 4-benzyloxy-3,5-dibromobenzyl alcohol 

Downstream Products

• 210824-99-0 N-(4-benzyloxy-3,5-dibromobenzyl)-8-oxoadenosine 
• 210825-00-6 N-(4-benzyloxy-3,5-dibromobenzyl)-2'-deoxy-8-oxoadenosine 
• 210825-01-7 N-(4-benzyloxy-3,5-dibromobenzyl)-8-oxoadenine 

Relevant articles and documents

Synthesis and structure of the marine ascidian 8-oxoadenine aplidiamine

Alkylation of 8-oxoadenosine (13) with 4-benzyloxy-3,5-dibromobenzyl bromide (20), followed by Dimroth rearrangement and acid hydrolysis, provided N-(3,5-dibromo-4-hydroxybenzyl)-8-oxoadenosine (15). The 2'- deoxy version of this reaction sequence accomplished the first synthesis of N-(3,5-dibromo-4- hydroxybenzyl)-8-oxoadenine (16), which is the correct expression for marine ascidian purine aplidiamine.