101191-32-6

Basic information

• Product Name: tetrakis(2-methylphenyl)osmium(IV)
• Synonyms: tetrakis(2-methylphenyl)osmium(IV)
• CAS NO: 101191-32-6
• Molecular Weight: 554.73
• Mol File: 101191-32-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: tetrakis(2-methylphenyl)osmium(IV)(CAS DataBase Reference)
• NIST Chemistry Reference: tetrakis(2-methylphenyl)osmium(IV)(101191-32-6)
• EPA Substance Registry System: tetrakis(2-methylphenyl)osmium(IV)(101191-32-6)

Safety Data

• Hazardous Substances Data: 101191-32-6(Hazardous Substances Data)

Upstream product

• 932-31-0 ortho-tolylmagnesium bromide 
• 20816-12-0 osmium(VIII) oxide 
• 672-66-2 Dimethyl(phenyl)phosphine 
• 2564-83-2 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical 
• 143-66-8 sodium tetraphenyl borate 

Downstream Products

• 7440-22-4 silver 
• 120022-43-7 Os{η6-2-(2-MeC6H4)MeC6H4}(2-MeC6H4)2(CO) 
• 120022-48-2 cis-Os(2-MeC₆H₄){CN(2,6-Me₂C₆H₃)}4 
• 120022-49-3 fac-Os(C,N-3-Me{2-C(2-MeC₆H₄)NC(2,6-Me₂C₆H₃)}C₆H₃)(2-MeC₆H₄){CN(2,6-Me₂C₆H₃)}3 
• 120022-44-8 cis-Os(2-MeC₆H₄)2(t-BuNC)4 

Relevant articles and documents

Redox Chemistry of the Homoleptic Aryl Os(2-MeC6H4)4: Synthesis and Characterization of the First Osmium(v) Organometallic

Oxidation of Os(2-MeC6H4)4 in CH2Cl2 gives the remarkably stable osmum(v)tetra-aryl salts, , (Y=BF4-, CF3SO3-); the triflate salt has been characterized by X-ray crystallography.

Mechanistic studies of ligand-induced thermolytic reductive elimination of biaryl from tetraarylosmium(IV)

The reaction of new tetraarylosmium(IV) complexes Os(2,4-Me2C6H3)4 and Os(4-F-2-MeC6H3)4 with PMe3 and P(OMe)3 has been investigated, as have the reactions between Os(

The Synthesis and X-Ray Crystal Structures of Homoleptic Tetrahedral Aryls of Osmium(IV) and of Cyclohexyls of Ruthenium(IV), Osmium(IV), and Chromium(IV)

The interactions of o-tolylmagnesium bromide or AlPh3(OEt2) with osmium tetraoxide leads to the isolation of the homoleptic, tetrahedral osmium(IV) compounds OsR4 (R = C6H4Me-o or C6H5).Thermally stable M(C6H11)4 compounds (M = Ru, Os, or Cr; C6H11 = cycl