101047-40-9

Basic information

• Product Name: Silane, trimethyl[2-(2-nitrophenyl)ethenyl]-, (E)-
• CAS NO: 101047-40-9
• Molecular Formula: C11H15NO2Si
• Molecular Weight: 221.331
• Mol File: 101047-40-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[2-(2-nitrophenyl)ethenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[2-(2-nitrophenyl)ethenyl]-, (E)-(101047-40-9)
• EPA Substance Registry System: Silane, trimethyl[2-(2-nitrophenyl)ethenyl]-, (E)-(101047-40-9)

Safety Data

• Hazardous Substances Data: 101047-40-9(Hazardous Substances Data)

Upstream product

• 609-73-4 o-nitroiodobenzene 
• 754-05-2 ethenyltrimethylsilane 
• 18107-18-1 diazomethyl-trimethyl-silane 

Relevant articles and documents

PALLADIUM-CATALYSED ARYLATION OF VINYLTRIMETHYLSILANE IN THE PRESENCE OF SILVER NITRATE

A series of arylated vinyltrimethylsilanes have been prepared by means of Heck Arylation in the presence of silver nitrate, which serves to suppress the elimination of the silicon group and enhance the reaction rate.

Synthesis of (E)-(2-Arylethenyl)silanes by Palladium-Catalyzed Arylation of Vinylsilanes in the Presence of Silver Nitrate

A series of (E)-trimethyl(2-arylethenyl)silanes 1-16 and (E)-triethoxy(2-arylethenyl)silanes 17 and 18 has been synthesized by palladium-catalyzed arylation of the corresponding vinylsilanes, in the presence of silver nitrate.Apart from enhancing the rate of the reaction, silver nitrate also completely suppresses the desilylation.In the absence of silver salt, under ordinary Heck arylation conditions, styrene derivatives are formed in good yields.A possible mechanistic rationale for the formation of styrenes is discussed.