(3-Phenoxyphenyl)methanol

Base Information

• Chemical Name: (3-Phenoxyphenyl)methanol
• CAS No.: 13826-35-2
• Deprecated CAS: 185532-86-9
• Molecular Formula: C13H12O2
• Molecular Weight: 200.237
• Hs Code.: 29062990
• European Community (EC) Number: 237-525-1
• UNII: 04964J25DQ
• DSSTox Substance ID: DTXSID7027756
• Nikkaji Number: J60.251E
• Wikidata: Q18409953
• Metabolomics Workbench ID: 62266
• ChEMBL ID: CHEMBL1869836
• Mol file: 13826-35-2.mol

Synonyms:(3-phenoxyphenyl)methanol;3-phenoxybenzyl alcohol;3-phenoxybenzylalcohol

Chemical Property of (3-Phenoxyphenyl)methanol

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 0.1 mm Hg ( 37.7 °C)
• Melting Point: 4-7°C
• Refractive Index: 1.5930
• Boiling Point: 377.8 °C at 760 mmHg
• PKA: 14.19±0.10(Predicted)
• Flash Point: 151.3 °C
• PSA: 29.46000
• Density: 1.151 g/cm³
• LogP: 2.97120
• Storage Temp.: Store below +30°C.
• Water Solubility.: Insoluble
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 200.083729621
• Heavy Atom Count: 15
• Complexity: 175

Purity/Quality:

98% ^*data from raw suppliers

3-Phenoxybenzyl Alcohol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, Xi
• Hazard Codes: Xn,Xi
• Statements: 22
• Safety Statements: 26-36/37-29

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Other Aromatic Compounds
• Canonical SMILES: C1=CC=C(C=C1)OC2=CC=CC(=C2)CO
• Uses: 3-Phenoxybenzyl alcohol has been used in the synthesis of 3-phenoxylbenzyl β-D-glucuronide.

Technology Process of (3-Phenoxyphenyl)methanol

There total 32 articles about (3-Phenoxyphenyl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.2%

methanolic potassium hydroxide + 3-phenoxybenzyl acetate (50789-44-1) → 3-Phenoxybenzyl alcohol (13826-35-2)

Guidance literature:

Reference yield: 95.0%

3-phenoxybenzyl acetate (50789-44-1) → 3-Phenoxybenzyl alcohol (13826-35-2)

Guidance literature:

With hydrogenchloride; sodium hydroxide; In methanol; dichloromethane; water;

Reference yield: 95.0%

2-(3-phenoxy-benzyloxy)-tetrahydro-pyran → 3-Phenoxybenzyl alcohol (13826-35-2)

Guidance literature:

With copper dichloride; In methanol; at 20 ℃;

DOI:10.1080/00397910008086870

upstream raw materials:

3-Phenoxybenzaldehyde

3-phenoxytoluene

3-phenoxybenzoic acid

3-Hydroxybenzyl alcohol

Downstream raw materials:

m-phenoxybenzyl adamantane-1-carboxylate

3-phenoxybenzyl (+/-)-cis,trans-3-formyl-2,2-dimethylcyclopropanecarboxylate

Eksmin

cis-Permethrin

Refernces

• 1、 Subba Reddy,Srinivas,Yadav,Ramalingam. "KF-Al2O3 mediated cross-Cannizzaro reaction under microwave irradiation". . p. 219 - 223. Retrieved 2002.
• 2、 Audino, Paola Gonzalez,Licastro, Susana A.,Zerba, Eduardo. "Thermal decomposition and isomerization of cis-permethrin and β-cypermethrin in the solid phase". . p. 183 - 189. Retrieved 2002.
• 3、 -. "IMPROVED METHOD FOR THE SYNTHESIS OF PERMETHRIN". Page/Page column 7; 8. . Retrieved 2018/03/25.