Thiocarbonic acid diphenyl ester

Base Information

• Chemical Name: Thiocarbonic acid diphenyl ester
• CAS No.: 13509-34-7
• Molecular Formula: C13H10 O2 S
• Molecular Weight: 230.287
• Hs Code.: 2930909090
• Mol file: 13509-34-7.mol

Synonyms:Carbonicacid, thio-, O,O-diphenyl ester (7CI,8CI); Diphenyl thionocarbonate; NSC328395; O,O-Diphenyl thiocarbonate; O,O'-Diphenyl thiocarbonate

Chemical Property of Thiocarbonic acid diphenyl ester

Chemical Property:

• Vapor Pressure: 0.000872mmHg at 25°C
• Melting Point: 106 °C
• Boiling Point: 314.2°C at 760 mmHg
• Flash Point: 143.8°C
• PSA: 50.55000
• Density: 1.232g/cm³
• LogP: 3.42930

Purity/Quality:

99% ^*data from raw suppliers

DIPHENOXYMETHANETHIONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thiocarbonic acid diphenyl ester

There total 22 articles about Thiocarbonic acid diphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

phenylcarbonochloridothioate (1005-56-7) → diphenylthiocarbonate (13509-34-7)

Guidance literature:

With potassium tert-butylate; In dichloromethane; at 20 ℃; Reagent/catalyst;

DOI:10.1055/s-0033-1338744

Reference yield: 90.0%

thiophosgene (463-71-8) + phenol (108-95-2,27073-41-2) → diphenylthiocarbonate (13509-34-7)

Guidance literature:

With triethylamine; In diethyl ether; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/jacs.8b03071

Reference yield: 82.0%

aniline (62-53-3) + phenylcarbonochloridothioate (1005-56-7) → diphenylthiocarbonate (13509-34-7)

Guidance literature:

With potassium tert-butylate; In dichloromethane; at 20 ℃;

DOI:10.1055/s-0033-1338744

upstream raw materials:

O-(2-naphthyl) O-phenyl thiocarbonate

sodium phenoxide

phenylcarbonochloridothioate

phenol

Downstream raw materials:

phenolate

3-β-phenethyl-5,5-diphenoxy-1,4,2-oxathiazole

3-(4-methoxyphenyl)-5,5-diphenoxy-1,4,2-oxathiazole

O-phenyl chlorothionoformate

Refernces

• 1、 Hamachi, Leslie S.,Jen-La Plante, Ilan,Coryell, Aidan C.,De Roo, Jonathan,Owen, Jonathan S.. "Kinetic Control over CdS Nanocrystal Nucleation Using a Library of Thiocarbonates, Thiocarbamates, and Thioureas". . p. 8711 - 8719. Retrieved 2017/10/30.
• 2、 Hewitt, Russell J.,Ong, Michelle Jui Hsien,Lim, Yi Wee,Burkett, Brendan A.. "Investigations of the Thermal Responsiveness of 1,4,2-Oxathiazoles". supporting information. p. 6687 - 6700. Retrieved 2015/10/29.