Technology Process of Cu(C8H3N2SO2NH(C6H11))4
There total 3 articles about Cu(C8H3N2SO2NH(C6H11))4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
thionyl chloride;
In
chloroform;
stirring mixt. of Cu(PC) and ClSO3H (3 h, 138-140°C), then with thionyl chloride (3 h, 80-85°C), cooling, pouring onto ice, filtration, ppt. washing (cold water), pressing, drying, mixing with amine soln., stirring (24 h, 25-30°C); repeated chromy. (aluminum oxide, chloroform/benzene 2:1); elem. anal.;
- Guidance literature:
-
With
urea;
ammonium molybdate;
In
further solvent(s);
mixt. of dinitrile, copper acetylacetonate, CuO, urea and catalytic amount of ammonium molybdate stirring for 4 h at 200-205°C in trichlorobenzene; suspn. chromy. (silica gel, eluent chloroform); elem. anal.;
- Guidance literature:
-
In
N,N-dimethyl-formamide;
mixt. of dibromo derivative, cuprous cyanide and DMF boiling for 5 h, cooling, pptn. on diln. (water); ppt. filtration off, washing (water), drying, chromy. (silica gel, chloroform), impurities hot extn. (methanol); elem. anal.;