[Al(O(p-C₆H₄Ph))(2-(2H-benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-pentylphenol(-1H))2]

Base Information

• Chemical Name: [Al(O(p-C₆H₄Ph))(2-(2H-benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-pentylphenol(-1H))2]
• CAS No.: 1206697-22-4
• Molecular Formula: C₅₆H₆₅AlN₆O₃
• Molecular Weight: 897.152
• Mol file: 1206697-22-4.mol

Synonyms:

Chemical Property of [Al(O(p-C₆H₄Ph))(2-(2H-benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-pentylphenol(-1H))2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Al(O(p-C₆H₄Ph))(2-(2H-benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-pentylphenol(-1H))2]

There total 1 articles about [Al(O(p-C₆H₄Ph))(2-(2H-benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-pentylphenol(-1H))2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4-Phenylphenol (92-69-3) + trimethylaluminum (75-24-1) + tinuvin 328 (25973-55-1) → [Al(O(p-C6H4Ph))(2-(2H-benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-pentylphenol(-1H))2] (1206697-22-4)

Guidance literature:

In toluene; (N2); using Schlenk techniques; addn. of soln. of HOC6H2(C5H11)2C6H4N3 in MePh to stirred soln. of AlMe3 in MePh at -78°C; warming to room temp.; reflux for 1 h; removal of solvent (vac.); dissolving in MePh; addn. of 4-Ph-phenol; reflux for 1 h; removal of all volatiles under vac., washing with n-hexane 3 times; dissolving in CH2Cl2/hexane; cooling at -20°C for a few ds; crystn.; elem. anal.;

DOI:10.1021/om9007423

upstream raw materials:

4-Phenylphenol

trimethylaluminum

tinuvin 328

Refernces