TRICYCLOHEXYL BORATE

Base Information

• Chemical Name: TRICYCLOHEXYL BORATE
• CAS No.: 1088-01-3
• Molecular Formula: C18H33B
• Molecular Weight: 260.271
• Hs Code.: 2931900090
• Mol file: 1088-01-3.mol

Synonyms:CTK0G7595;Borane,tricycloheptyl;tricyclohexylborane;Tricycloheptylboran;AGN-PC-00NRWH;ACMC-20m5fr;Tricyclohexyl-boran;Tricyclohexylbor;

Chemical Property of TRICYCLOHEXYL BORATE

Chemical Property:

• Vapor Pressure: 4.07E-05mmHg at 25°C
• Boiling Point: 362.3oC at 760 mmHg
• Flash Point: 172.9oC
• PSA: 0.00000
• Density: 0.89g/cm3
• LogP: 6.48410

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRICYCLOHEXYL BORATE

There total 21 articles about TRICYCLOHEXYL BORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

cyclohexane (110-82-7,25012-93-5) + diborane (19287-45-7) → tricyclohexylborane (1088-01-3)

Guidance literature:

In gas; Irradiation (UV/VIS); irradiation of B2H6/CH2CHCH3 mixture (1:3) with a pulsed CO2 laser (944.2 1/cm, 31 pulses);

DOI:10.1016/0584-8539(90)80150-W

Reference yield: 64.0%

Li(1+)*(C5H5)Fe(C5H4BH3)(1-)*O(C2H5)2=Li(C5H5)Fe(C5H4BH3)*O(C2H5)2 (1195790-78-3) + cyclohexene (110-83-8) → tricyclohexylborane (1088-01-3) + cyclohexyldi(ferrocenyl)borane (1195790-67-0)

Guidance literature:

With chloro-trimethyl-silane; In diethyl ether; byproducts: (CH3)3SiH; (Schlenk, N2) (CH3)3SiCl in diethyl ether was added dropwise with stirring at -78°C to a soln. of complex and cyclohexene in diethyl ether, allowed to warm to room temp., stirred for 1 h,; filtered, washed with diethyl ether, evapd. to dryness under vac., dissolved in min warm heptane, the soln. was stored at -30°C for 12 h;elem. anal.;

DOI:10.1021/ja906575s

Reference yield:

triethylamine-borane (1722-26-5) + cyclohexene (110-83-8) → tricyclohexylborane (1088-01-3) + triethylamine (121-44-8)

Guidance literature:

In neat (no solvent); heating to 200°C in an autoclave;;

DOI:10.1021/ja01527a010

upstream raw materials:

triisobutylborane

cyclohexane

cyclohexylmagnesium bromide

cyclohexene

Downstream raw materials:

2-cyclohexyl-1,3,2-dioxaborolane

n-pentylcyclohexylacetylene

2-cyclohexylquinoline

1-cyclohexyl-1-(trimethylsilyl)methanol

Refernces

• 1、 Brown,Subba Rao. "-". . p. 6423,6425. Retrieved 1959.
• 2、 Horino, Yoshikazu,Sugata, Miki,Abe, Hitoshi. "Palladium-Catalyzed Three-Component Reaction of 3-(Tri-n- butylstannyl)allyl Acetates, Aldehydes, and Triorganoboranes: An Alternative to the Carbonyl Allylation Using α,γ-Substituted Allylic Tin Reagents". supporting information. p. 1023 - 1028. Retrieved 2016/04/19.
• 3、 Andreou, Anna,Leskes, Michal,Jambrina, Pablo G.,Tustin, Gary J.,Grey, Clare P.,Rosta, Edina,Scherman, Oren A.. "Divergence from the classical hydroboration reactivity; boron containing materials through a hydroboration cascade of small cyclic dienes". . p. 6262 - 6269. Retrieved 2015/10/28.