Zn(1,4-benzenedicarboxylate)(H₂O)

Base Information

• Chemical Name: Zn(1,4-benzenedicarboxylate)(H₂O)
• CAS No.: 98499-48-0
• Molecular Formula: C₈H₄O₄*H₂O*Zn
• Molecular Weight: 247.523
• Mol file: 98499-48-0.mol

Synonyms:

Chemical Property of Zn(1,4-benzenedicarboxylate)(H₂O)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zn(1,4-benzenedicarboxylate)(H₂O)

There total 5 articles about Zn(1,4-benzenedicarboxylate)(H₂O) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.4%

terephthalic acid (100-21-0) + zinc(II) acetate dihydrate (5970-45-6) → Zn(1,4-benzenedicarboxylate)(H2O) (98499-48-0,866925-97-5)

Guidance literature:

In N,N-dimethyl-formamide; Sonication; ligand in DMF mixed with Zn salt in DMF, ultrasonicated at room temp. for 10-90 min; centrifuged, washed (H2O, EtOH), dried at room temp.(vac.) for 12 h;

DOI:10.1016/j.inoche.2008.09.010

Reference yield: 36.1%

zinc(II) nitrate hexahydrate + terephthalic acid (100-21-0) → Zn(1,4-benzenedicarboxylate)(H2O) (98499-48-0,866925-97-5)

Guidance literature:

With 1-butyl-3-methylimidazolium chloride; at 160 ℃; for 5h; Reagent/catalyst; Temperature; Autoclave;

DOI:10.1039/c5dt02672e

Reference yield:

[Zn(1,4-benzenedicarboxylate)(H2O)]*DMF (213275-65-1) → Zn(1,4-benzenedicarboxylate)(H2O) (98499-48-0,866925-97-5)

Guidance literature:

In methanol; immersion of Zn complex in MeOH for 3 d;

DOI:10.1002/anie.200906965

upstream raw materials:

zinc(II) acetate dihydrate

disodium terephthalate

terephthalic acid

[Zn(1,4-benzenedicarboxylate)(H₂O)]*DMF

Downstream raw materials:

[zinc(1,4-benzenedicarboxylate)(H₂O)2]

[Zn(1,4-benzenedicarboxylate)(H₂O)]*DMF

[zinc(1,4-benzenedicarboxylate)(1,4-diazabicyclo[2.2.2]octane)(H₂O)]

Zn(1,4-benzenedicarboxylate)(4,4'-bipyridine)

Refernces

• 1、 Zhang, Zong-Hui,Liu, Bing,Xu, Ling,Jiao, Huan. "Combination effect of ionic liquid components on the structure and properties in 1,4-benzenedicarboxylate based zinc metal-organic frameworks". . p. 17980 - 17989. Retrieved 2015/10/28.
• 2、 Li, Zong-Qun,Qiu, Ling-Guang,Wang, Wei,Xu, Tao,Wu, Yun,Jiang, Xia. "Fabrication of nanosheets of a fluorescent metal-organic framework [Zn(BDC)(H2O)]n (BDC = 1,4-benzenedicarboxylate): Ultrasonic synthesis and sensing of ethylamine". . p. 1375 - 1377. Retrieved 2009/02/07.