Technology Process of [(μ5-C5H5)Re(NO)(CO)(P(C6F5)3)]BF4
There total 1 articles about [(μ5-C5H5)Re(NO)(CO)(P(C6F5)3)]BF4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
neat (no solvent);
all manipulations under dry N2 atm.; complex and the phosphane heated at140°C, after 27 h further phosphane was added and mixt. was heat ed for another 23 h; cooled, extd. with MeCN, extract filtered through Celite and concd., addn. of hexane/ether, ppt. filtered off, washed with hexane and CH2Cl2/hexane, dried in vac.; elem. anal.;
- Guidance literature:
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In
methanol;
all manipulations under dry N2 atm.; mixt. of complex and MeOH cooled to0°C, addn. of MeONa, stirred for 2 h at 0°C; ppt. filtered off, washed with MeOH and water, dried in vac.; elem. anal.;
- Guidance literature:
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In
tetrahydrofuran;
all manipulations under dry N2 atm.; addn. of NaBH4 to complex in THF with stirring; after 10 min THF was removed, benzene was added; mixt. was filtered, solvent was removed from filtrate under vac., residue suspended in cold pentane, filtered, dried in vac.; elem. anal.;
![[(η(5)-C5H5)Re(NO)(CO)(MeCN)]BF4](/Databaselist/images/loading.webp)
