(Dimethylphenylphosphine)gold chloride

Base Information

• Chemical Name: (Dimethylphenylphosphine)gold chloride
• CAS No.: 28978-09-8
• Molecular Formula: C8H11AuCl3P
• Molecular Weight: 370.569
• Mol file: 28978-09-8.mol

Synonyms:(Dimethylphenylphosphine)gold chloride

Chemical Property of (Dimethylphenylphosphine)gold chloride

Chemical Property:

• Melting Point: 98-102°C
• PSA: 13.59000
• LogP: -0.94510

Purity/Quality:

99% ^*data from raw suppliers

Chloro(dimethylphenylphosphine)gold 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of (Dimethylphenylphosphine)gold chloride

There total 9 articles about (Dimethylphenylphosphine)gold chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium tetrachloroaurate(III) (15189-51-2) + Dimethyl(phenyl)phosphine (672-66-2) → (dimethylphenylphosphine)gold(I) chloride (28978-09-8)

Guidance literature:

In not given; byproducts: C6H5(CH3)2PO; 2 equiv. of phosphine; elem. anal.;

DOI:10.1039/DT9790001730

Reference yield: 87.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + Dimethyl(phenyl)phosphine (672-66-2) → (dimethylphenylphosphine)gold(I) chloride (28978-09-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃; Inert atmosphere; Glovebox;

DOI:10.1021/acs.jmedchem.0c01926

Reference yield: 78.0%

gold(III) tetrachloride trihydrate + Dimethyl(phenyl)phosphine (672-66-2) → (dimethylphenylphosphine)gold(I) chloride (28978-09-8)

Guidance literature:

With thiodiglycol; In ethanol; acetone; (N2), HAuCl4*3H2O in EtOH cooled to 0°C, treated with thiodiglycol in EtOH, color vanished, PPhMe2 in acetone was added, stirred for 1h; concd. slowly;

upstream raw materials:

Dimethyl(phenyl)phosphine

sodium tetrachloroaurate(III)

Dichloromethylsilane

diphenylsilyl chloride

Downstream raw materials:

{HFe₄(CO)12Au₂(P(CH₃)2(C₆H₅))2B}

{HFe₄(CO)12Au₂((P(CH₃)(C₆H₅)2))2B}

{HFe₄(CO)12Au₂(PCH₃(C₆H₅)2)(P(CH₃)2(C₆H₅))B}

((C₆H₅)(CH₃)2PSe)((C₆H₅)3P)Au⁽¹⁺⁾*SbF₆^(1-) = {((C₆H₅)(CH₃)2PSe)Au(P(C₆H₅)3)}SbF₆

Refernces

• 1、 Cerrada, Elena,Laguna, Mariano,Lardies, Nora. "Bis(1,2,3-thiadiazole)s as precursors in the synthesis of bis(alkynethiolate)gold(I) derivatives". . p. 137 - 146. Retrieved 2009/04/13.
• 2、 Meyer, Juergen,Willnecker, Johannes,Schubert, Ulrich. "Transition-Metal Silyl Complexes, 26. - Gold(I) Silyl Complexes". . p. 223 - 230. Retrieved 2007/10/02.