(R)-Ru(OAc)2(BINAP)

Base Information

• Chemical Name: (R)-Ru(OAc)2(BINAP)
• CAS No.: 325146-81-4
• Molecular Formula: C₄₈H₃₈O₄P₂Ru
• Molecular Weight: 841.845
• Hs Code.: 28439000
• European Community (EC) Number: 689-262-0,815-432-2
• Mol file: 325146-81-4.mol

Synonyms:(R)-Ru(OAc)2(BINAP);325146-81-4;261948-85-0;acetic acid;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium;DIACETATO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II);104713-03-3;MFCD09753020;DIACETATO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II);Ru(BINAP)(OAc)2;Bis(acetato)(binap)ruthenium;(S)-Ru(OAc)2(BINAP;Bis(acetato)(binap) ruthenium;SC10141;SY010588;SY010589;F16636;Diacetato[(S)-()-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);(R)-{1-[2-(diphenylphosphanyl)naphthalen-1-yl]naphthalen-2-yl}diphenylphosphane (acetyloxy)ruthenio acetate;Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), Ru(OAc)2[(R)-binap]

Chemical Property of (R)-Ru(OAc)2(BINAP)

Chemical Property:

• Appearance/Colour: pale yellow powder.
• Melting Point: >100°C
• PSA: 79.78000
• LogP: 8.66860
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 7
• Exact Mass: 844.144524
• Heavy Atom Count: 55
• Complexity: 875

Purity/Quality:

98% ^*data from raw suppliers

Ru(OAc)2[(R)-binap] ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=O)O.CC(=O)O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru]
• Uses: (R)-Ru(OAc)2(BINAP) is a catalyst.

Technology Process of (R)-Ru(OAc)2(BINAP)

There total 10 articles about (R)-Ru(OAc)2(BINAP) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

[bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II) + (R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene (76189-55-4,76189-56-5,98327-87-8) + acetic acid (64-19-7,77671-22-8) → bis(acetato){(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}rutenium(II) (325146-81-4,104713-03-3,114818-52-9,104621-48-9,261948-85-0)

Guidance literature:

In toluene; N2, a soln. of Ru compd. and P compd. refluxed for 4 h, solvent evapd. (vac.), ether soln. of acetic acid added at room temp., stirred for 10-14h; elem. anal.;

DOI:10.1016/j.molcata.2003.10.016

Reference yield: 86.0%

[(η6-C6H6)RuCl2] (35796-48-6) + sodium acetate (127-09-3) + (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl (76144-87-1,76189-55-4,76189-56-5,98327-87-8,136655-44-2) → bis(acetato){(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}rutenium(II) (325146-81-4,104713-03-3,114818-52-9,104621-48-9,261948-85-0)

Guidance literature:

[(η6-C6H6)RuCl2]; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; In N,N-dimethyl-formamide; at 100 ℃; for 1.5h; Inert atmosphere; Schlenk technique;

sodium acetate; In methanol; N,N-dimethyl-formamide; for 0.333333h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201809719

Reference yield:

(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene (76189-55-4,76189-56-5,98327-87-8) + dichloro(1,5-cyclooctadiene)ruthenium(II) → bis(acetato){(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}rutenium(II) (325146-81-4,104713-03-3,114818-52-9,104621-48-9,261948-85-0)

Guidance literature:

With sodium acetate; triethylamine; In toluene; tert-butyl alcohol; react. of (RuCl2(cod))2 with (R)-BINAP and N(C2H5)3 in toluene, then addn. of NaO2CCH3;;

upstream raw materials:

(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene

acetic acid

[(η6-C6H6)RuCl2]

sodium acetate

Downstream raw materials:

(η6-benzamide)[1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydridoruthenium(II) trifluoromethanesulfonate

[1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydrido[(η6-phenyl)acetone]ruthenium(II) trifluoromethanesulfonate

[1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydrido[1-(η6-phenyl)ethanol]ruthenium(II) trifluoromethanesulfonate

[1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P'](η6-chlorobenzene)hydridoruthenium(II) trifluoromethanesulfonate

Refernces

• 1、 -. "METHOD FOR PRODUCING A RUTHENIUM COMPLEX". Page/Page column 7. . Retrieved 2010/04/23.
• 2、 Brunner, Henri,Fisch, Konrad. "Asymmetrische Katalysen. LXXXII. Enantioselektive Hydrierung von 4-Oxoisophoron". . p. 71 - 75. Retrieved 2007/10/02.