Bis(tri-tert-butylphosphine)platinum(0)

Base Information

• Chemical Name: Bis(tri-tert-butylphosphine)platinum(0)
• CAS No.: 60648-70-6
• Molecular Formula: C24H54P2Pt
• Molecular Weight: 599.72
• DSSTox Substance ID: DTXSID80421971
• Mol file: 60648-70-6.mol

Synonyms:60648-70-6;Bis(tri-tert-butylphosphine)platinum(0);Bis(tri-t-butylphosphine)platinum (0);BIS(TRI-T-BUTYLPHOSPHINE)PLATINUM(0);platinum;tritert-butylphosphane;Bis[tris(1,1-dimethylethyl)phosphine]platinum;SCHEMBL5575777;HEPTANEDIOICACIDDIHYDRAZIDE;DTXSID80421971;MFCD04974248;AKOS016009903;SC10683;B3162;D81811;Platinum-tris(2-methyl-2-propanyl)phosphine (1:2);BIS(TRI-T-BUTYLPHOSPHINE)PLATINUM (O);BIS(TRI-TERT-BUTYLPHOSPHINE)PLATINUM(0);BIS[TRIS(1,1-DIMETHYLETHYL)PHOSPHINE]PLATINUM

Chemical Property of Bis(tri-tert-butylphosphine)platinum(0)

Chemical Property:

• Vapor Pressure: 0.105mmHg at 25°C
• Melting Point: 260-269 °C
• Boiling Point: 229.4 °C at 760 mmHg
• Flash Point: 94.6 °C
• PSA: 27.18000
• LogP: 9.72510
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 599.334870
• Heavy Atom Count: 27
• Complexity: 128

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bis(tri-tert-butylphosphine)platinum(0) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pt]
• Uses: Reactant for synthesis of:Trimetallic ReBiPt complexesRhodium-germanium carbonyl complexesCatalyst for the synthesis of:Amidobipyridyl inhibitors of protein kinase D5-Fluoroalkylated pyrimidine nucleosides via Negishi cross-couplingCatalyst for phenyl and methyl group transfer from tin to iridiumActivator of metal hydride complexes

Technology Process of Bis(tri-tert-butylphosphine)platinum(0)

There total 17 articles about Bis(tri-tert-butylphosphine)platinum(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II) (67901-08-0) → bis(tri-tert-butylphosphine)platinum(0) (60648-70-6)

Guidance literature:

With sodium methylate; In methanol; soln. of Pt complex in benzene was added to MeOH soln. of MeONe; stirring for 5 h; evapn., extn. with pentane, evapn.;

Reference yield: 90.0%

trans-PtHBr[P(t-Bu)3]2 (67871-27-6) → bis(tri-tert-butylphosphine)platinum(0) (60648-70-6)

Guidance literature:

With potassium hydroxide; In ethanol; benzene; soln. of Pt complex in benzene was treated with EtOH soln. of KOH; react. time 1 h; evapn., recrystn.;

Reference yield: 90.0%

trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II) (67901-08-0) → trans-bis(tri-tert-butylphosphine)platinum(II) dihydride (67870-05-7,1013923-81-3) + bis(tri-tert-butylphosphine)platinum(0) (60648-70-6)

Guidance literature:

With sodium tetrahydroborate; In ethanol; NaBH4 was added to stirred soln. of Pt complex; stirring for 30 min; evapn., extn. with pentane, evapn., recrystn. from hexane; elem. anal.;

upstream raw materials:

trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II)

Tris((tert-butylimino){tert-butyl(trimethylsilyl)amino}phosphane)platinum⁽⁰⁾

tri-tert-butyl phosphine

trans-bis(tri-tert-butylphosphine)platinum(II) dihydride

Refernces

• 1、 Liberman-Martin, Allegra L.,Levine, Daniel S.,Ziegler, Micah S.,Bergman, Robert G.,Tilley, T. Don. "Lewis acid-base interactions between platinum(II) diaryl complexes and bis(perfluorophenyl)zinc: Strongly accelerated reductive elimination induced by a Z-type ligand". supporting information. p. 7039 - 7042. Retrieved 2016/06/09.
• 2、 Denmark, Scott E.,Wang, Zhigang,Keller, Adam I.,Curran, Dennis P.. "Platinum catalyzed hydrosilylation and palladium catalyzed cross-coupling: One-pot hydroarylation of 1-heptyne to (E)-1-(1-heptenyl)-4-methoxybenzene :[Benzene, 1-(1e)-1-heptenyl-4-methoxy-]". . p. 54 - 62. Retrieved 2017/09/27.