Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II)

Base Information

• Chemical Name: Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II)
• CAS No.: 506417-41-0
• Molecular Formula: C₂₈H₃₂Cl₂N₂P₂Ru
• Molecular Weight: 630.499
• Hs Code.: 28439090
• European Community (EC) Number: 623-516-3
• DSSTox Substance ID: DTXSID30584787
• Mol file: 506417-41-0.mol

Synonyms:506417-41-0;Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II);Dichlorobis[2-(diphenylphosphino)ethylamine]ruthenium(II);dichlororuthenium;2-diphenylphosphanylethanamine;SCHEMBL1767611;DTXSID30584787;MFCD07782004;AKOS015900275;F72876;dichlorobis[2-(diphenylphosphino)ethylamine]ruthenium (ii);2-(Diphenylphosphanyl)ethan-1-amine--dichlororuthenium (2/1);Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II), 95%;DICHLOROBIS[2-(DIPHENYLPHOSPHINO-KAPPAP)ETHANAMINE-KAPPAN]RUTHENIUM

Chemical Property of Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II)

Chemical Property:

• Melting Point: 130-135°C
• PSA: 79.22000
• LogP: 6.93560
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 8
• Exact Mass: 630.046119
• Heavy Atom Count: 35
• Complexity: 168

Purity/Quality:

95% ^*data from raw suppliers

Dichlorobis[2-(diphenylphosphino)ethylamine]ruthenium(II), min. 95% (mixture of isomers) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(CCN)C2=CC=CC=C2.C1=CC=C(C=C1)P(CCN)C2=CC=CC=C2.Cl[Ru]Cl
• Uses: Catalyst for:Synthesis of long chain linear fatty acid estersPreparation of ruthenium borohydride complexes for use in hydrogenation reactionsDehydrogenation of ammonia boranesChemoselective reduction of carboxylic estersSynthesis of ruthenium beta-aminophosphine hydrido/chloro complexes with catalytic activities

Technology Process of Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II)

There total 3 articles about Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + (2-aminoethyl)diphenylphosphane (4848-43-5) → [RuCl2(Ph2PCH2CH2NH2)2] (404890-21-7,506417-41-0)

Guidance literature:

In toluene; at 100 ℃; for 6h; Glovebox; Schlenk technique;

Reference yield: 77.0%

bis-μ-dichloro(1,5-cyclooctadiene)ruthenium(II) + 2-(diphenylphosphino)ethylammonium tetrafluoroborate → RuCl2(Ph2PCH2CH2NH2)2 (404890-21-7,506417-41-0)

Guidance literature:

With triethylamine; In toluene; for 16h; Inert atmosphere; Reflux;

Reference yield:

(2-aminoethyl)diphenylphosphane (4848-43-5) → [RuCl2(Ph2PCH2CH2NH2)2] (404890-21-7,506417-41-0)

Guidance literature:

In toluene; for 12h; Inert atmosphere; Schlenk technique; Glovebox; Reflux;

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

(2-aminoethyl)diphenylphosphane

Downstream raw materials:

trans-[ruthenium(dihydride)(Ph₂PC₂H₄NH₂)2]

Refernces

• 1、 -. "CATALYSTS AND PROCESSES FOR THE HYDROGENATION OF AMIDES". Paragraph 0214; 0215; 0216. . Retrieved 2014/06/24.
• 2、 -. "METHOD FOR PREPARING A METAL CATALYST". Page/Page column 12. . Retrieved 2012/03/10.