O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate

Base Information

• Chemical Name: O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate
• CAS No.: 91496-28-5
• Molecular Formula: C₁₂H₁₄O₂S₂
• Molecular Weight: 254.374
• Mol file: 91496-28-5.mol

Synonyms:O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate

Chemical Property of O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate

There total 5 articles about O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

potassium ethyl xanthogenate (140-89-6) + 4-(bromoacetyl)toluene (619-41-0) → O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate (91496-28-5)

Guidance literature:

4-(bromoacetyl)toluene; With sodium iodide; In acetone; at 20 ℃; for 0.166667h;

potassium ethyl xanthogenate; In acetone; at 20 ℃; for 0.333333h;

DOI:10.1039/c9ob00701f

Reference yield: 86.0%

C16H16N3O2(1+)*CF3O3S(1-) + potassium ethyl xanthogenate (140-89-6) → O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate (91496-28-5)

Guidance literature:

In acetonitrile; for 16h; Inert atmosphere;

DOI:10.1021/acs.orglett.5b01120

Reference yield:

potassium ethyl xanthogenate (140-89-6) → O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate (91496-28-5)

Guidance literature:

In acetone; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1055/s-0036-1588706

upstream raw materials:

potassium ethyl xanthogenate

4-(bromoacetyl)toluene

1-ethenyl-4-methylbenzene

Downstream raw materials:

bis-ethoxythiocarbonyldisulfane

1,4-bis(4-tolyl)butane-1,4-dione

C₂₀H₃₂O₅S₂Si

C₂₃H₃₈O₅S₂Si

Refernces

• 1、 Abdellaoui, Hassane,Chen, Xingpeng,Xu, Jiaxi. "Efficient Synthesis of N-Benzyloxycarbonyl-2-aminoalkanesulfonyl Chlorides with Functionalized Side Chains". . p. 2250 - 2256. Retrieved 2017/05/05.
• 2、 Andia, Alexander A.,Miner, Matthew R.,Woerpel. "Copper(I)-catalyzed oxidation of alkenes using molecular oxygen and hydroxylamines: Synthesis and reactivity of α-oxygenated ketones". . p. 2704 - 2707. Retrieved 2015/06/16.