NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT

Base Information

• Chemical Name: NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT
• CAS No.: 29046-78-4
• Molecular Formula: C4H10 Cl2 Ni O2
• Molecular Weight: 219.718
• Mol file: 29046-78-4.mol

Synonyms:Nickel,dichloro(1,2-dimethoxyethane)- (8CI); Nickel,dichloro(1,2-dimethoxyethane-O,O')-; Dichloro(1,2-dimethoxyethane)nickel;Dichloro(dimethoxyethane)nickel

Chemical Property of NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT

Chemical Property:

• Melting Point: >300 °C
• PSA: 18.46000
• LogP: 1.65820
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: moisture sensitive

Purity/Quality:

98% ^*data from raw suppliers

Nickel(II)chlorideethyleneglycoldimethylether ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 23/24/25-36/37/38-42/43-45-50/53-43-36/38-25
• Safety Statements: 26-36/37/39-61-60-45-36/37-53

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Nickel(II) chloride ethylene glycol dimethyl ether is commonly used as a catalyst for the synthesis of various organic compounds. Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.

Technology Process of NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT

There total 4 articles about NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

nickel(II) chloride dihydrate + orthoformic acid triethyl ester (122-51-0) → (1,2-dimethoxyethane)dichloronickel(II) (29046-78-4)

Guidance literature:

In 1,2-dimethoxyethane; (N2), refluxed (2 h); cooled, ppt. filtered, washed (pentane), dried (inert atmosphere);

DOI:10.1016/S0022-328X(00)99541-X

Reference yield: 80.0%

1,2-dimethoxyethane (110-71-4) + nickel dichloride (83864-14-6) → (1,2-dimethoxyethane)dichloronickel(II) (29046-78-4)

Guidance literature:

In further solvent(s); (Schlenk techniques); NiCl2 dissolved in MeOH/trimethyl orthoformate, refluxed overnight, filtered, concd. (vac.), dissolved in MeOH, DME added,refluxed overnight; filtered, washed (pentane), dried (N2); elem. anal.;

DOI:10.1021/om7008759

Reference yield: 74.0%

1,2-dimethoxyethane (110-71-4) + nickel(II) chloride hexahydrate → (1,2-dimethoxyethane)dichloronickel(II) (29046-78-4)

Guidance literature:

nickel(II) chloride hexahydrate; at 130 ℃; Schlenk technique; Inert atmosphere;

1,2-dimethoxyethane; With orthoformic acid triethyl ester; for 2.5h; Schlenk technique; Inert atmosphere; Reflux;

DOI:10.1016/j.jorganchem.2012.07.044

upstream raw materials:

1,2-dimethoxyethane

nickel dichloride

orthoformic acid triethyl ester

Downstream raw materials:

NiCl₂{2-(diphenylphosphino)-N-((1-methyl-1H-imidazol-2-yl)methylene)ethanamine}

1.2-(Cl₂Ni(P(C₆H₅)2)2)-1.2-C₂B₁₀H₁₀

cis-NiCl₂(9,9-(Ph₂POCH₂)2-fluorene)*CH₂Cl₂

(Cl₃PdPPh₂C₅H₄)Fe(C₅H₄C₅H₂N(C₅H₄N)2NiCl(dmso)2)

Refernces

• 1、 Kermagoret, Anthony,Braunstein, Pierre. "Mono- and dinuclear nickel complexes with phosphino-, phosphinito-, and phosphonitopyridine ligands: Synthesis, structures, and catalytic oligomerization of ethylene". . p. 88 - 99. Retrieved 2008/10/09.
• 2、 Masotti, H.,Wallet, J. C.,Pfeiffer, G.. "DIMERISATION DE MONOOLEFINES CATALYSEE PAR DES COMPLEXES DU NICKEL ET DU COBALT GENERES ELECTROCHIMIQUEMENT". . p. 241 - 252. Retrieved 2007/10/02.