SODIUM TETRAKIS(4-FLUOROPHENYL)BORATE

Base Information

• Chemical Name: SODIUM TETRAKIS(4-FLUOROPHENYL)BORATE
• CAS No.: 25776-12-9
• Molecular Formula: C24H16 B F4 . Na
• Molecular Weight: 414.185
• Hs Code.: 2931900090
• Mol file: 25776-12-9.mol

Synonyms:Borate(1-),tetrakis(4-fluorophenyl)-, sodium (9CI); Borate(1-), tetrakis(p-fluorophenyl)-,sodium (8CI); Sodium tetrakis(p-fluorophenyl)borate (7CI); Benzene, fluoro-,boron complex; NSC 123496; Sodium tetrakis(4-fluorophenyl)borate

Chemical Property of SODIUM TETRAKIS(4-FLUOROPHENYL)BORATE

Chemical Property:

• PSA: 0.00000
• LogP: 3.62040
• Storage Temp.: Refrigerator
• Water Solubility.: almost transparency

Purity/Quality:

98%,99%, ^*data from raw suppliers

Sodium Tetrakis(4-fluorophenyl)borate Hydrate[Precipitation reagent for Cs and titrimetric reagent for nonionic surfactants] >98.0%(HPLC)(W) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Tetrakis(4-Fluorophenyl)-Borate Sodium (1:1) is a useful research chemical compound.

Technology Process of SODIUM TETRAKIS(4-FLUOROPHENYL)BORATE

There total 5 articles about SODIUM TETRAKIS(4-FLUOROPHENYL)BORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium tetrafluoroborate (13755-29-8) + 1-Bromo-4-fluorobenzene (460-00-4) → sodium tetrakis(4-fluorophenyl)borate (25776-12-9)

Guidance literature:

With magnesium; In tetrahydrofuran; at 0 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1055/s-0035-1560476

Reference yield:

1-Bromo-4-fluorobenzene (460-00-4) → sodium tetrakis(4-fluorophenyl)borate (25776-12-9)

Guidance literature:

1-Bromo-4-fluorobenzene; With magnesium; ethylene dibromide; In diethyl ether; at 20 ℃; for 1.5h; Inert atmosphere;

With sodium tetrafluoroborate; In diethyl ether; at 20 ℃; for 32h; Inert atmosphere;

DOI:10.1002/anie.201000937

Reference yield:

sodium tetrafluoroborate (13755-29-8) + 4-flourophenylmagnesium bromide (352-13-6) → sodium tetrakis(4-fluorophenyl)borate (25776-12-9)

Guidance literature:

With sodium chloride; In diethyl ether; water; pouring the reaction mixture into ice-cold satd. aq. NaCl soln.; extrn. with ether; addn. of xylene and removing the ether;

upstream raw materials:

sodium tetrafluoroborate

lithium

1-Bromo-4-fluorobenzene

4-flourophenylmagnesium bromide

Downstream raw materials:

4,4'-difluorobiphenyl

4-methyl-4'-fluorobiphenyl

tris(4-fluorophenyl)bismuthane

C₂₁H₁₉FO

Refernces

• 1、 Osuka, Atsuhiro,Vasu, Dhananjayan,Yorimitsu, Hideki. "Base-free palladium-catalyzed cross-coupling of arylsulfonium salts with sodium tetraarylborates". . p. 3286 - 3291. Retrieved 2020/10/20.
• 2、 Zhou, Wen-Jun,Wang, Ke-Hu,Wang, Jin-Xian,Gao, Zhi-Rong. "Ligand-free, atom-efficient Suzuki-Miyaura type cross-coupling reactions at room temperature". experimental part. p. 7633 - 7641. Retrieved 2010/12/19.