4-methoxyphenyl 4-nitrophenyl anhydride

Base Information

• Chemical Name: 4-methoxyphenyl 4-nitrophenyl anhydride
• CAS No.: 109258-04-0
• Molecular Formula: C₁₅H₁₁NO₆
• Molecular Weight: 301.255
• Mol file: 109258-04-0.mol

Synonyms:4-methoxyphenyl 4-nitrophenyl anhydride

Chemical Property of 4-methoxyphenyl 4-nitrophenyl anhydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methoxyphenyl 4-nitrophenyl anhydride

There total 4 articles about 4-methoxyphenyl 4-nitrophenyl anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

4-methoxy-benzoyl chloride (100-07-2) + 4-nitro-benzoic acid (62-23-7) → 4-methoxyphenyl 4-nitrophenyl anhydride (109258-04-0)

Guidance literature:

With triethylamine; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1021/jo0621975

Reference yield: 81.0%

4-nitro-benzoyl chloride (122-04-3) + 4-methoxybenzoic acid (100-09-4) → 4-methoxyphenyl 4-nitrophenyl anhydride (109258-04-0)

Guidance literature:

With Fe/SWCNTs; at 20 ℃; for 1.33333h;

DOI:10.1002/adsc.201000365

Reference yield:

p-methoxybenzoic p-nitrophenyldiazoacetic anhydride (847557-07-7) → p-anisic p-nitrobenzoylformic anhydride + 4-methoxyphenyl 4-nitrophenyl anhydride (109258-04-0)

Guidance literature:

With 9,10-diphenylanthracene; oxygen; dirhodium tetraacetate; In benzene; at 30 ℃; for 1h; Title compound not separated from byproducts; UV-irradiation;

DOI:10.1021/jo0621975

upstream raw materials:

4-nitro-benzoyl chloride

4-methoxybenzoic acid

4-methoxy-benzoyl chloride

4-nitro-benzoic acid

Refernces

• 1、 Hamaguchi, Masashi,Tomida, Naoki,Iyama, Yuji. "Reaction of electron-deficient N=N, N=O double bonds, singlet oxygen, and CC triple bonds with acyloxyketenes or mesoionic 1,3-dioxolium-4-olates: Generation of unstable mesoionic 1,3-dioxolium-4-olates from acyloxyketenes". . p. 1326 - 1334. Retrieved 2007/10/03.