M-TOLYLMAGNESIUM BROMIDE

Base Information

• Chemical Name: M-TOLYLMAGNESIUM BROMIDE
• CAS No.: 28987-79-3
• Molecular Formula: C7H7 Br Mg
• Molecular Weight: 195.342
• Hs Code.: 29319090
• Mol file: 28987-79-3.mol

Synonyms:Magnesium,bromo-m-tolyl- (7CI,8CI); m-Tolylmagnesium bromide (6CI);3-Methylphenylmagnesium bromide; 3-Tolylmagnesium bromide;Bromo(3-methylphenyl)magnesium; Bromo-m-tolylmagnesium; Toluene-3-magnesiumbromide; m-Methylphenylmagnesium bromide

Chemical Property of M-TOLYLMAGNESIUM BROMIDE

Chemical Property:

• Flash Point: -17°C (THF)
• PSA: 0.00000
• LogP: 2.64080

Purity/Quality:

99% ^*data from raw suppliers

3-Methylphenylmagnesium bromide ^*data from reagent suppliers

Safty Information:

• Statements: 11-14/15-19-34
• Safety Statements: 16-26-43-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of M-TOLYLMAGNESIUM BROMIDE

There total 3 articles about M-TOLYLMAGNESIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

meta-bromotoluene (591-17-3) → m-tolylmagnesium bromide (28987-79-3)

Guidance literature:

With magnesium; In tetrahydrofuran; ethylene dibromide; at 0 ℃;

Reference yield:

meta-bromotoluene (591-17-3) + magnesium (7439-95-4) → m-tolylmagnesium bromide (28987-79-3)

Guidance literature:

In tetrahydrofuran; Inert atmosphere;

DOI:10.1021/ol5018273

Reference yield:

→ m-tolylmagnesium bromide (28987-79-3)

Guidance literature:

upstream raw materials:

meta-bromotoluene

magnesium

Downstream raw materials:

2-(3-methylphenyl)ethanol

acetic acid-[2-(α-hydroxy-3,3'-dimethyl-benzhydryl)-anilide]

9-(3-Methylphenyl)xanthen-9-ol

2-(4-ethoxy-phenyl)-3-m-tolyl-inden-1-one

Refernces

• 1、 Deng, Yuchao,Wei, Xiao-Jing,Wang, Xiao,Sun, Yuhan,No?l, Timothy. "Iron-Catalyzed Cross-Coupling of Alkynyl and Styrenyl Chlorides with Alkyl Grignard Reagents in Batch and Flow". supporting information. p. 14532 - 14535. Retrieved 2019/11/21.
• 2、 Yang, Wanfei,Chen, Huoji,Li, Jianxiao,Li, Chunsheng,Wu, Wanqing,Jiang, Huanfeng. "Palladium-catalyzed aerobic oxidative double allylic C-H oxygenation of alkenes: A novel and straightforward route to α,β-unsaturated esters". supporting information. p. 9575 - 9578. Retrieved 2015/06/08.