1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Base Information

• Chemical Name: 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
• CAS No.: 213343-64-7
• Molecular Formula: C30H48BF4P2Rh-
• Molecular Weight: 660.36
• Hs Code.: 28439000
• European Community (EC) Number: 811-349-0
• Mol file: 213343-64-7.mol

Synonyms:213343-64-7;MFCD01862465;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Et-DUPHOS-Rh;1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;AKOS005146312;AT21795;1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) tetrafluoroborate

Chemical Property of 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Chemical Property:

• PSA: 27.18000
• LogP: 10.57580
• Sensitive.: air sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 6
• Exact Mass: 660.23154
• Heavy Atom Count: 38
• Complexity: 414

Purity/Quality:

98%,99%, ^*data from raw suppliers

(S,S)-Et-DUPHOS-Rh ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [B-](F)(F)(F)F.CCC1CCC(P1C2=CC=CC=C2P3C(CCC3CC)CC)CC.C1CC=CCCC=C1.[Rh]
• Isomeric SMILES: [B-](F)(F)(F)F.CC[C@H]1CC[C@@H](P1C2=CC=CC=C2P3[C@H](CC[C@@H]3CC)CC)CC.C1CC=CCCC=C1.[Rh]
• Uses: (S,S)-Et-DUPHOS-Rh is a catalyst in the asymmetric preparation of B precursor of cryptophycin, and in the synthesis of constrained phenylalanine analogs. DuPhos and BPE Ligands: Highly Efficient Privileged LigandsCatalyst for:Preparation of a key unit B precursor of cryptophycins via Horner-Wadsworth-Emmons reaction and asymmetric hydrogenationPreparation of constrained phenylalanine analogs via Heck reaction followed by asymmetric hydrogenation and cyclization stepsEnantioselective preparation of N-benzyloxy-β-amino acid Me esters by hydrogenation of α-(benzyloxyaminomethyl)acrylate stereoisomersPreparation of fluoro amino acids as synthons for potent macrocyclic HCV NS3 protease inhibitorsStereoselective preparation of triply isotope-labeled Ser, Cys, and AlaPreparation of β-amino acids from asymmetric hydrogenation of α-(aminomethyl)acrylatesAsymmetric hydrogenation of a-primary and secondary amino ketones and asymmetric synthesis of (-)-arbutamine and (-)-denopamine