Aluminum fluoride hydrate

Base Information

• Chemical Name: Aluminum fluoride hydrate
• CAS No.: 32287-65-3
• Molecular Formula: AlF₃*3H₂O
• Molecular Weight: 138.023
• European Community (EC) Number: 621-168-7
• DSSTox Substance ID: DTXSID40583428
• Mol file: 32287-65-3.mol

Synonyms:Aluminum fluoride hydrate;32287-65-3;trifluoroalumane;hydrate;ALUMINIUM FLUORIDE HYDRATE;13462-92-5;Aluminum fluoride (AlF3), trihydrate (9CI);ALUMINIUM FLUORIDE MONOHYDRATE, EXTRA PURE, 99.999per cent;aluminum trifluoride hydrate;Trifluoroalumane--water (1/1);DTXSID40583428

Chemical Property of Aluminum fluoride hydrate

Chemical Property:

• Melting Point: 250 °C
• Boiling Point: 19.5°Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: g/cm³
• LogP: 1.19630
• Water Solubility.: slightly soluble H2O [CRC10]
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 101.9873126
• Heavy Atom Count: 5
• Complexity: 8

Purity/Quality:

98%Min ^*data from raw suppliers

ALUMINUM FLUORIDE HYDRATE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 25-36/37/38
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: O.F[Al](F)F

Technology Process of Aluminum fluoride hydrate

There total 18 articles about Aluminum fluoride hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aluminum arsenide + Carbonyl fluoride (353-50-4) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → arsenic (7440-38-2,460345-38-4,7784-42-1,127323-69-7) + aluminum hexaaqua(III) ion (15453-67-5) + aluminium(III) fluoride trihydrate (32287-65-3) + AlF(2+) + AlF3*3H2O, rosenbergite (32287-65-3)

Guidance literature:

In water; GaAs substrate with AlAs layer milled, powder treated with HF; solid analyzed with XRD, AlF(2+), Al(H2O)6(3+) and AlF(x)(H2O)(6-x)((3-x)+) species detd. with (27)Al and (19)F NMR; AsH3 detd. with chromy.; Kinetics;

DOI:10.1149/1.1690293

Reference yield:

aluminum arsenide + Carbonyl fluoride (353-50-4) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → arsenic (7440-38-2,460345-38-4,7784-42-1,127323-69-7) + aluminum hexaaqua(III) ion (15453-67-5) + aluminium(III) fluoride trihydrate (32287-65-3) + AlF(2+) + AlF3*3H2O, rosenbergite (32287-65-3)

Guidance literature:

In water; GaAs substrate with AlAs layer milled, powder treated with HF; solid analyzed with XRD, AlF(2+), Al(H2O)6(3+) and AlF(x)(H2O)(6-x)((3-x)+) species detd. with (27)Al and (19)F NMR; AsH3 detd. with chromy.; Kinetics;

DOI:10.1149/1.1690293

Reference yield:

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + aluminum acetate (139-12-8) → fluellite (13462-92-5,32287-65-3)

Guidance literature:

evaporate to dryness;

upstream raw materials:

aluminum(III) fluoride

hydrogen fluoride

aluminum acetate

fluorosilicic acid

Refernces

• 1、 Kleist, Wolfgang,Hae?ner, Carmen,Storcheva, Oksana,K?hler, Klaus. "A simple aqueous phase synthesis of high surface area aluminum fluoride and its bulk and surface structure". . p. 4851 - 4854. Retrieved 2006.
• 2、 Vimont, Alexandre,Lavalley, Jean-Claude,Francke, Lo?c,Demourgues, Alain,Tressaud, Alain,Daturi, Marco. "Infrared Study of the Surface Properties of HTB-Type Al-, Cr-, Fe-Hydroxyfluorides". . p. 3246 - 3255. Retrieved 2007/10/03.