Chlorodi(1-naphthyl)phosphine

Base Information

• Chemical Name: Chlorodi(1-naphthyl)phosphine
• CAS No.: 36042-99-6
• Molecular Formula: C20H14 Cl P
• Molecular Weight: 320.751921
• Hs Code.: 2903999090
• European Community (EC) Number: 679-370-6
• DSSTox Substance ID: DTXSID50595739
• Wikidata: Q82490815
• Mol file: 36042-99-6.mol

Synonyms:36042-99-6;Chlorodi(1-naphthyl)phosphine;Bis(1-naphthyl)chlorophosphine,;BIS(1-NAPHTHYL)CHLOROPHOSPHINE;chloro(dinaphthalen-1-yl)phosphane;chlorobis(naphthalen-1-yl)phosphane;MFCD09753469;Phosphinous chloride, di-1-naphthalenyl-;Di(1-naphthyl)chlorophosphine;SCHEMBL2516404;DTXSID50595739;ZHRMSAAMUUNWKE-UHFFFAOYSA-N;Dinaphthalen-1-ylphosphinous chloride;AKOS016015603;SY075175;CS-0106672

Chemical Property of Chlorodi(1-naphthyl)phosphine

Chemical Property:

• Vapor Pressure: 9.21E-10mmHg at 25°C
• Melting Point: 154-157°C
• Boiling Point: 227-229°C/0.6mm
• Flash Point: 258.2°C
• PSA: 13.59000
• Density: g/cm³
• LogP: 5.57950
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Reacts with water.
• XLogP3: 6.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 320.0521651
• Heavy Atom Count: 22
• Complexity: 337

Purity/Quality:

95% ^*data from raw suppliers

Bis(1-naphthyl)chlorophosphine, min. 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC=C2P(C3=CC=CC4=CC=CC=C43)Cl

Technology Process of Chlorodi(1-naphthyl)phosphine

There total 2 articles about Chlorodi(1-naphthyl)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromonaphthalene (90-11-9) → chlorobis(α-naphthyl)phosphine (36042-99-6)

Guidance literature:

1-Bromonaphthalene; With tert.-butyl lithium; In cyclohexane; pentane; at 0 - 20 ℃; for 15h;

In diethyl ether; at 20 ℃; for 1h; Further stages.;

DOI:10.1002/adsc.200600503

Reference yield:

→ chlorobis(α-naphthyl)phosphine (36042-99-6)

Guidance literature:

1-Naphthylchlorid, P, All3;

DOI:10.1021/jo00912a027

Reference yield: 88.0%

(RC,SFc,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene + chlorobis(α-naphthyl)phosphine (36042-99-6) → (RC,SFc,SP)-1-[2-(1-N,N-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-di(1-naphthyl)phosphinoferrocene

Guidance literature:

(R_C,S_Fc,S_P)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene; With n-butyllithium; In hexane; tert-butyl methyl ether; at -5 - 0 ℃;

chlorobis(α-naphthyl)phosphine; In hexane; tert-butyl methyl ether; at 0 - 20 ℃;

DOI:10.1002/anie.201304472

upstream raw materials:

1-Bromonaphthalene

Downstream raw materials:

bis(1-naphthyl)-N,N-bis-[(S)-1-phenyl-ethyl]phosphinamine

Refernces