1-Butyl-3-methylimidazolium methanesulfonate

Base Information

• Chemical Name: 1-Butyl-3-methylimidazolium methanesulfonate
• CAS No.: 342789-81-5
• Molecular Formula: C9H18N2O3S
• Molecular Weight: 234.32
• Hs Code.: 29332900
• European Community (EC) Number: 679-383-7
• ChEMBL ID: CHEMBL3187191
• DSSTox Substance ID: DTXSID9047912
• Mol file: 342789-81-5.mol

Synonyms:1-Butyl-3-methylimidazolium methanesulfonate;342789-81-5;DTXSID9047912;1-butyl-3-methylimidazol-3-ium;methanesulfonate;MFCD06798173;1-Butyl-3-methyl-1H-imidazolium methanesulfonate;SCHEMBL193628;C9H18N2O3S;CHEMBL3187191;DTXCID2027888;PUHVBRXUKOGSBC-UHFFFAOYSA-M;Tox21_200589;AKOS015898254;CS-W014162;NCGC00258143-01;BS-44010;1-butyl-3-methylimidazolium methylsulfonate;1-butyl-3-methylimidazolium methanesulphonate;B3231;CAS-342789-81-5;FT-0761019;1-n-butyl-3-methylimidazolium methanesulfonate;D88993;1-BUTYL-3-METHYLIMIDAZOLIUMMETHANESULFONATE;A875038;Q-102680;1-Butyl-3-methylimidazolium methanesulfonate, >=95%;1-Butyl-3-methylimidazolium methanesulfonate, for energy applications

Chemical Property of 1-Butyl-3-methylimidazolium methanesulfonate

Chemical Property:

• Melting Point: 75-80 °C
• Flash Point: 119 °C
• PSA: 74.39000
• LogP: 1.35490
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: soluble in Methanol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 234.10381361
• Heavy Atom Count: 15
• Complexity: 173

Purity/Quality:

99% ^*data from raw suppliers

1-Butyl-3-methylimidazolium methanesulfonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C,T
• Statements: 22-34-52/53-25
• Safety Statements: 26-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCN1C=C[N+](=C1)C.CS(=O)(=O)[O-]
• Uses: Capacitor technology, sensors, optical devices, magnetic fluids1,2 1-Butyl-3-methylimidazolium methanesulfonate can be used:To prepare a deep eutectic solvent applicable in the ammonia sorption.As a solvent in the high-pressure CO2 removal process.To prepare ionic liquid/phosphomolybdate based hybrids as catalysts applicable in the glucose epimerization.

Technology Process of 1-Butyl-3-methylimidazolium methanesulfonate

There total 16 articles about 1-Butyl-3-methylimidazolium methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methanesulfonic acid (75-75-2,98527-29-8) + 1-butyl-3-methyl-1H-imidazol-3-ium methylcarbonate (916850-37-8) → 1-n-butyl-3-methylimidazolium methanesulfonate (342789-81-5)

Guidance literature:

In methanol; at 0 - 20 ℃; for 1h;

DOI:10.1016/j.electacta.2021.137865

Reference yield: 100.0%

methanesulfonic acid (75-75-2,98527-29-8) + 1-methyl-3-(n-butyl)imidazolium iodide (65039-05-6) → 1-n-butyl-3-methylimidazolium methanesulfonate (342789-81-5)

Guidance literature:

methanesulfonic acid; With Amberlyst A-26 (OH^- form); In methanol; water; at 20 ℃;

1-methyl-3-(n-butyl)imidazolium iodide; In methanol;

DOI:10.3390/molecules17044007

Reference yield: 100.0%

1-methyl-3-(n-butyl)imidazolium iodide (65039-05-6) → 1-n-butyl-3-methylimidazolium methanesulfonate (342789-81-5)

Guidance literature:

In methanol; Ionic liquid; solid phase reaction;

DOI:10.1039/b915743n

upstream raw materials:

1-Butylimidazole

Ethyl methanesulfonate

1-methyl-1H-imidazole

n-butyl methanesulfonate

Downstream raw materials:

1-methyl-1H-imidazole

1-Butylimidazole

1-butyl-3-methylimidazolium trifluoromethanesulfonimide

1-(n-butyl)-3-methylimidazolium triflate

Refernces

• 1、 Loguercio, Lara F.,De Matos, Carolina F.,De Oliveira, Matheus C.,Marin, Graciane,Khan, Sherdil,Balzaretti, Naira M.,Dupont, Jairton,Leite Santos, Marcos J.,Leite Santos, Jacqueline F.. "Synergistic interplay of ionic liquid and dodecyl sulphate driving the oxidation state of polypyrrole based electrodes". . p. 13828 - 13835. Retrieved 2018.
• 2、 Ketsomboon, Nutthanicha,Saeeng, Rungnapha,Srisook, Klaokwan,Sirion, Uthaiwan. "Convenient synthesis of long alkyl-chain triazolylglycosides using ionic liquid as dual promoter-solvent: Readily access to non-ionic triazolylglycoside surfactants for evaluation of cytotoxic activity". . . Retrieved 2021/08/26.
• 3、 Li, Wenxiu,Dai, Shangwu,Li, Dong,Zhang, Qinqin,Fan, Hongtao,Zhang, Tao,Zhang, Zhigang. "Redox Reaction: A New Route for the Synthesis of Water-Miscible Imidazolium Ionic Liquids". . p. 1065 - 1072. Retrieved 2017/02/23.