benzyl <2-²H3>ethanoate

Base Information

• Chemical Name: benzyl <2-²H3>ethanoate
• CAS No.: 114379-93-0
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 153.153
• Mol file: 114379-93-0.mol

Synonyms:benzyl <2-²H3>ethanoate

Chemical Property of benzyl <2-²H3>ethanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of benzyl <2-²H3>ethanoate

There total 22 articles about benzyl <2-²H3>ethanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

C29H31NO4 → benzyl <2-2H3>ethanoate (114379-93-0) + C29H32(2)HNO4 + benzyl 4-cyclohexyl-2,5-dimethyl-1H-pyrrole-3-carboxylate

Guidance literature:

With boron trifluoride diethyl etherate; tetrabutylammonium tetrafluoroborate; water-d2; In tetrahydrofuran; at 20 ℃; for 12h; Electrolysis; Inert atmosphere;

DOI:10.1039/d1gc00487e

Reference yield:

tetradeuterioacetic acid (1186-52-3) + C22H28O4S → benzyl tosylate (1024-41-5) + benzyl <2-2H3>ethanoate (114379-93-0) + C17H21(2)H3O3 + C8H14O

Guidance literature:

at 23 ℃; for 11h; Solvolysis;

DOI:10.1002/anie.201410043

Reference yield:

DCCOCH2C6H5 (114379-91-8) + water-d2 (7789-20-0) + sulfuric acid-d2 (13813-19-9) → benzyl <2-2H3>ethanoate (114379-93-0)

Guidance literature:

With mercury(II) chloride; In water-d2;

upstream raw materials:

(benzyloxy)acetylene

tetradeuterioacetic acid

benzyl chloride

benzyl alcohol

Downstream raw materials:

tetradeuterioacetic acid

d⁽³⁾-acetic acid

Refernces

• 1、 Garcia, Angie,Otte, Douglas A. L.,Sanzone, Jillian R.,Woerpel, K. A.,Salamant, Walter A.. "Acceleration of acetal hydrolysis by remote alkoxy groups: Evidence for electrostatic effects on the formation of oxocarbenium ions". supporting information. p. 3061 - 3064. Retrieved 2015/05/05.
• 2、 Gill, Harjit K.,Smith, Roland W.,Whiting, Donald A.. "Ring D Expansion and Aromatisation in the Biosynthesis of Nic-1, an Antifeedant Steroid from Nicandra physaloides". . p. 2989 - 2993. Retrieved 2007/10/02.