Tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tin hydride

Base Information

• Chemical Name: Tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tin hydride
• CAS No.: 175354-32-2
• Molecular Formula: C₂₄H₁₃F₃₉Sn
• Molecular Weight: 1161.01
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID90893529
• Wikidata: Q82871304
• Mol file: 175354-32-2.mol

Synonyms:Tris((perfluorohexyl)ethyl)stannane;Tris(1h,1h,2h,2h-perfluorooctyl)tinhydride;(C6F13CH2CH2)3SnH;SCHEMBL1526947;DTXSID90893529;XDEOXVCAUPQFMU-UHFFFAOYSA-N;Tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tin hydride;Tris(2-(perfluorohexyl)ethyl)tin Hydride;Tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tin hydride, ~90%

Chemical Property of Tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tin hydride

Chemical Property:

• Vapor Pressure: 9.66E-07mmHg at 25°C
• Boiling Point: 133-40°C/0.02mmHg
• Flash Point: 205.3°C
• PSA: 0.00000
• LogP: 14.60020
• Storage Temp.: >-5° C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 39
• Rotatable Bond Count: 21
• Exact Mass: 1161.941651
• Heavy Atom Count: 64
• Complexity: 1400

Purity/Quality:

99% ^*data from raw suppliers

Tris(1H,1H,2H,2H-perfluorooctyl)tin hydride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38-53
• Safety Statements: 61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(C[SnH](CCC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)CCC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of Tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tin hydride

There total 6 articles about Tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tin hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)bromostannane → tris(1H,1H,2H,2H-perfluorooctyl)tin hydride (175354-32-2)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 0 - 1 ℃; for 6.75h; Inert atmosphere;

DOI:10.15227/orgsyn.079.0001

Reference yield:

tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)bromostannane + Rochelle's salt (304-59-6) → tris(1H,1H,2H,2H-perfluorooctyl)tin hydride (175354-32-2)

Guidance literature:

With LiAlH₄; In water;

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)bromostannane → tris(1H,1H,2H,2H-perfluorooctyl)tin hydride (175354-32-2)

Guidance literature:

In diethyl ether;

DOI:10.1021/ja953287m

upstream raw materials:

Rochelle's salt

lithium aluminium tetrahydride

bromine

phenyltin trichloride

Refernces

• 1、 -. "Fluorous reaction and separation systems". . . Retrieved 2008/06/13.
• 2、 -. "Fluorous reaction systems". . . Retrieved 2008/06/13.