(2-METHYLALLYL)AMINE HYDROCHLORIDE

Base Information

• Chemical Name: (2-METHYLALLYL)AMINE HYDROCHLORIDE
• CAS No.: 28148-54-1
• Molecular Formula: C4H9 N . Cl H
• Molecular Weight: 107.58
• Hs Code.: 2921199090
• European Community (EC) Number: 627-969-8
• DSSTox Substance ID: DTXSID00474606
• Mol file: 28148-54-1.mol

Synonyms:Allylamine,2-methyl-, hydrochloride (6CI,8CI); (2-Methylallyl)amine hydrochloride;2-Methyl-2-propen-1-amine hydrochloride

Chemical Property of (2-METHYLALLYL)AMINE HYDROCHLORIDE

Chemical Property:

• Vapor Pressure: 75.3mmHg at 25°C
• Melting Point: 179-184 °C(lit.)
• Boiling Point: 83.5°Cat760mmHg
• Flash Point: °C
• PSA: 26.02000
• Density: g/cm³
• LogP: 2.02350
• Storage Temp.: Store under Nitrogen
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 107.0501770
• Heavy Atom Count: 6
• Complexity: 38.9

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Methylallylamine hydrochloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)CN.Cl
• Uses: Reactant for:Preparation of platinum cyclometalated N-heterocyclic carbene complexes with chiral phosphines as catalystsPreparation of oxoazetidinylbutenyl acetamides via rhodium-catalyzed hydroformylationPreparation of highly monodisperse polymeric particles incorporating polymerizable perylene-bisimide fluorophoreAdditive-free chemoselective acylation with anhydrides for preparation of amides

Technology Process of (2-METHYLALLYL)AMINE HYDROCHLORIDE

There total 1 articles about (2-METHYLALLYL)AMINE HYDROCHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(1,3-dimethyl-2-oxo-2λ5-[1,3,2]diazaphospholidin-2-yl)-(2-methyl-allyl)-phosphoramidic acid diphenyl ester → 2-methylallylamine hydrochloride (28148-54-1)

Guidance literature:

With hydrogenchloride; In methanol; water;

DOI:10.1002/anie.200353284

Reference yield: 99.9%

2-methylallylamine hydrochloride (28148-54-1) + 4-methoxy-benzaldehyde (123-11-5) → N-(4-methoxybenzyl)-2-methylprop-2-en-1-amine

Guidance literature:

2-methylallylamine hydrochloride; 4-methoxy-benzaldehyde; In dichloromethane; at 20 ℃; for 3h; Molecular sieve;

With sodium tetrahydroborate; In ethanol; at 20 ℃; for 2h;

DOI:10.1039/c2cc35484e

Reference yield: 97.0%

2-methylallylamine hydrochloride (28148-54-1) + 4-chloro-benzoyl chloride (122-01-0) → 4-chloro-N-(2-methylallyl)benzamide (65296-17-5)

Guidance literature:

With triethylamine; In dichloromethane;

DOI:10.1139/v94-005

Downstream raw materials:

2-mercapto-3-(2-methyl-2-propenyl)thieno<3,2-d>pyrimidin-4(3H)-one

4-chloro-N-(2-methylallyl)benzamide

N-(diphenylmethylidene)-2-methyl-2-propenylimine

N-(4-methylbenzylidene)-2-methyl-2-propenylamine

Refernces

• 1、 Lee, Ernest E.,Batey, Robert A.. "Palladium-catalyzed [3,3] sigmatropic rearrangement of (allyloxy) iminodiazaphospholidines: Allylic transposition of C-O and C-N functionality". . p. 1865 - 1868. Retrieved 2007/10/03.