NITROGEN-15N DIOXIDE

Base Information

• Chemical Name: NITROGEN-15N DIOXIDE
• CAS No.: 14184-22-6
• Molecular Formula: NO₂
• Molecular Weight: 46.9988
• Mol file: 14184-22-6.mol

Synonyms:Nitrogendioxide (15NO2); Nitrogen dioxide-15N; Nitrogen-15 dioxide; Nitrogen-15Ndioxide

Chemical Property of NITROGEN-15N DIOXIDE

Chemical Property:

• PSA: 34.14000
• LogP: -0.41360

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of NITROGEN-15N DIOXIDE

There total 8 articles about NITROGEN-15N DIOXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

lead (15)N-nitrate → (15)N-nitrogen dioxide (14184-22-6,137496-65-2)

Guidance literature:

In not given; heating (all glass apparatus); collection in trap (-80°C);

DOI:10.1139/cjc-77-5-6-647

Reference yield:

sodium (15)N-nitrite (68378-96-1) + Nitrogen dioxide (10102-44-0) → (15)N-nitrogen dioxide (14184-22-6,137496-65-2) + sodium nitrite (7632-00-0)

Guidance literature:

With sodium hydroxide; In neat (no solvent); byproducts: NaNO3, Na(15)NO3; mixt. of NO2 and N2 flow through soln. of Na(15)NO2 and aq. NaOH; soln. analyzed by negative-ion FAB MS; Kinetics;

DOI:10.1021/ja00196a083

Reference yield:

oxygen (80937-33-3) + 15N labeled nitric oxide (15917-77-8) → (15)N-nitrogen dioxide (14184-22-6,137496-65-2)

Guidance literature:

In gas; fractionally distd.;

DOI:10.1021/ic700846x

upstream raw materials:

[⁽¹⁵⁾N]nitrite

Nitrogen dioxide

sodium ⁽¹⁵⁾N-nitrite

oxygen

Downstream raw materials:

sym-(15)NO3

dinitrogen pentoxide

meso-tetraphenylporphyrinato(η1-[(15)N]nitrito)iron(III)

meso-tetra-p-tolylporphyrinato(η1-[(15)N]nitrito)iron(III)

Refernces

• 1、 Kurtikyan, Tigran S.,Hovhannisyan, Astghik A.,Iretskii, Alexei V.,Ford, Peter C.. "Six-coordinate nitro complexes of iron(III) porphyrins with trans S-donor ligands. Oxo-transfer reactivity in the solid state". . p. 11236 - 11241. Retrieved 2009.
• 2、 Kurtikyan, Tigran S.,Hovhannisyan, Astghik A.,Gulyan, Gurgen M.,Ford, Peter C.. "Interaction of nitrogen bases with iron-porphyrin nitrito complexes Fe(Por)(ONO) in sublimed solids". . p. 7024 - 7031. Retrieved 2008/10/09.