Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct

Base Information

• Chemical Name: Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct
• CAS No.: 851232-71-8
• Molecular Formula: CH₂Cl₂*C₃₄H₂₈Cl₂FeP₂Pd
• Molecular Weight: 816.65
• Hs Code.: 28439000
• Mol file: 851232-71-8.mol

Synonyms:1,1-Bis(diphenylphosphino)ferrocene palladium(II) dichloride acetone adduct

Chemical Property of Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct

Chemical Property:

• Melting Point: 280℃
• PSA: 27.18000
• LogP: 9.18940
• Sensitive.: Air sensitive

Purity/Quality:

99% ^*data from raw suppliers

Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II) acetone adduct 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct

There total 1 articles about Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + cis-dichlorobis(benzonitrile)palladium(II) (14220-64-5,15617-18-2,39958-10-6) → dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 (95464-05-4,72287-26-4,851232-71-8)

Guidance literature:

In benzene; mixt. of soln. of Pd-compound in benzene and soln. of ferrocene derivative in benzene, stirred (12 h, 20°C); filtration, washed with a little benzene, evapn.; elem. anal.;

DOI:10.1016/S0020-1693(00)80550-2

Reference yield: 100.0%

dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 (95464-05-4,72287-26-4,851232-71-8) + 4-fluorophenylzinc chloride (133472-27-2) + methyl 2-amino-5-iodobenzoate (77317-55-6) → C16H16FNO2

Guidance literature:

In tetrahydrofuran; for 1.08333h;

Reference yield: 98.0%

silver hexafluoroantimonate (26042-64-8) + dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 (95464-05-4,72287-26-4,851232-71-8) + acetonitrile (75-05-8,26809-02-9) → bis(acetonitrile)[1,1′-bis(diphenylphosphino)ferrocene]palladium(II) hexafluoroantimonate

Guidance literature:

at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1039/c3cc43653e

upstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene

cis-dichlorobis(benzonitrile)palladium(II)