TRANS-4-TERT-PENTYLCYCLOHEXANOL

Base Information

• Chemical Name: TRANS-4-TERT-PENTYLCYCLOHEXANOL
• CAS No.: 20698-30-0
• Molecular Formula: C11H22O
• Molecular Weight: 170.295
• Hs Code.: 2906199090
• Mol file: 20698-30-0.mol

Synonyms:Cyclohexanol,4-tert-pentyl-, trans- (8CI);trans-4-tert-Amylcyclohexanol;

Chemical Property of TRANS-4-TERT-PENTYLCYCLOHEXANOL

Chemical Property:

• Melting Point: 24-27 °C
• Refractive Index: 1.471
• Boiling Point: 223.2 °C at 760 mmHg
• Flash Point: 90.5 °C
• PSA: 20.23000
• Density: 0.914 g/cm³
• LogP: 2.97370

Purity/Quality:

98%Min ^*data from raw suppliers

trans-4-(tert-Pentyl)cyclohexanol 95+% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRANS-4-TERT-PENTYLCYCLOHEXANOL

There total 6 articles about TRANS-4-TERT-PENTYLCYCLOHEXANOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.5%

4-t-amylphenol (80-46-6) → trans-4-tert-amylcyclohexano-1-ol (20698-30-0)

Guidance literature:

With potassium hydroxide; Raney Ni-Al; water; at 90 ℃; for 12h;

DOI:10.3184/030823409X393637

Reference yield: 5.0%

4-tert-amylcyclohexanone (16587-71-6) → trans-4-tert-amylcyclohexano-1-ol (20698-30-0) + 4-(2'-hydroxy)-tert-amylcyclohexanone + 4-(2-Hydroxy-1,1-dimethyl-propyl)-cyclohexanol + 4-(2-Hydroxy-1,1-dimethyl-propyl)-cyclohexanol

Guidance literature:

In ethanol; for 288h; Further byproducts given; 3 day old culture of Cephalosporium aphidicola;

Reference yield: 4.0%

4-tert-amylcyclohexanone (16587-71-6) → trans-4-tert-amylcyclohexano-1-ol (20698-30-0) + cis-4-tert-amylcyclohexano-1-ol (20698-29-7) + 4-(2'-hydroxy)-tert-amylcyclohexanone + 4-(2-Hydroxy-1,1-dimethyl-propyl)-cyclohexanol

Guidance literature:

In ethanol; for 288h; Further byproducts given; 3 day old culture of Cephalosporium aphidicola;

upstream raw materials:

4-t-amylphenol

4-tert-amylcyclohexanone

Downstream raw materials:

ethyl 1-((6-((cis-4-(tert-pentyl)cyclohexyl)oxy)naphthalen-2-yl)methyl)piperidine-4-carboxylate

Refernces

• 1、 Tan, Song-Liang,Liu, Guo-Bin,Gao, Xiang,Thiemann, Thies. "Raney Ni-Al alloy-mediated reduction of alkylated phenols in water". experimental part. p. 5 - 7. Retrieved 2009/09/06.