[1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride

Base Information

• Chemical Name: [1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride
• CAS No.: 59831-02-6
• Molecular Formula: C27H26Cl2P2Pd
• Molecular Weight: 589.777
• Hs Code.: 28439000
• European Community (EC) Number: 627-387-4
• Mol file: 59831-02-6.mol

Synonyms:59831-02-6;[1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride;Dichloro[1,3-bis(diphenylphosphino)propane]palladium(II);(1,3-Bis(diphenylphosphino)propane)palladium(II) chloride;MFCD03844773;dichloro(1,3-bis(diphenylphosphino)propane)palladium(ii);dichloropalladium;3-diphenylphosphanylpropyl(diphenyl)phosphane;[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) CHLORIDE;PdCl2(dippp);DICHLORO[BIS(1,3-DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II);pdcl2(dppp);PdCl2 dppp;Palladium, dichloro[1,3-propanediylbis[diphenylphosphine]-P,P']-, (SP-4-2)-;SCHEMBL1025432;LDFBXJODFADZBN-UHFFFAOYSA-L;AKOS015951026;AC-5514;GC10010;LS-0008;SY010258;A832490;dichloro-[1,3bis(diphenylphosphino)propane]palladium(ii);3-diphenylphosphinopropyl(diphenyl)phosphine;[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]DICHLOROPALLADIUM(II);bis(chloranyl)palladium

Chemical Property of [1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride

Chemical Property:

• Vapor Pressure: 9E-11mmHg at 25°C
• Boiling Point: 529.7 °C at 760 mmHg
• Flash Point: 291.5 °C
• PSA: 27.18000
• LogP: -0.34970
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Air Sensitive
• Solubility.: Soluble in dichloromethane.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 587.99216
• Heavy Atom Count: 32
• Complexity: 353

Purity/Quality:

99% ^*data from raw suppliers

[1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 36/37/38-20/21/22
• Safety Statements: 26-36/37/39-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(CCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Pd]Cl
• Uses: suzuki reaction (1,3-Bis(diphenylphosphino)propane)palladium(II) chloride, used ubiquitously as a employed preparation of palladium for cross-coupling protocols in organic synthesis. It is also a useful organo-metallic chemical catalyst. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is also used in coupling reactions.

Technology Process of [1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride

There total 18 articles about [1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + 1,3-bis-(diphenylphosphino)propane (6737-42-4) → dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II) (59831-02-6)

Guidance literature:

In dichloromethane; for 2h; Inert atmosphere;

DOI:10.1016/j.tetlet.2019.151202

Reference yield: 98.1%

hydrogenchloride (7647-01-0,15364-23-5) + 1,3-bis-(diphenylphosphino)propane (6737-42-4) + palladium (7440-05-3) → bis(diphenylphosphino)propanepalladium(II) dichloride (59831-02-6)

Guidance literature:

hydrogenchloride; palladium; With nitric acid; In water;

1,3-bis-(diphenylphosphino)propane; In water; N,N-dimethyl-formamide; at 50 ℃; for 1h;

Reference yield: 94.0%

1,3-bis-(diphenylphosphino)propane (6737-42-4) + palladium dichloride → bis(diphenylphosphino)propanepalladium(II) dichloride (59831-02-6)

Guidance literature:

With hydrogenchloride; In ethanol; dichloromethane; for 3h; Reflux;

DOI:10.13005/ojc/330205

upstream raw materials:

1,3-bis-(diphenylphosphino)propane

chlorobenzene

dichloro(1,5-cyclooctadiene)palladium(II)

hydrogenchloride

Downstream raw materials:

cis-Pd(SeCOPh)2(dppp)

[(4-methyl-C₆H₄COSe)2 (bis(diphenylphosphino)propane) palladium(II)]

[(μ-S,S-(N,N'-ethylenebis(2-thioacetamidate))nickelate(II))(1,3-bis(diphenylphosphanyl)propane)palladium(II)]

(((C₆H₅)2PCH₂)2CH₂)Pd(S₂C₂S₂CC₁₁H₆N₂)

Refernces

• 1、 Shanmugapriya,Dallemer,Prabhakaran. "Synthesis, characterisation, crystal structures and biological studies of palladium(ii) complexes containing 5-(2-hydroxy-3-methoxy-phenyl)-2,4-dihydro[1,2,4]triazole-3-thione derivatives". . p. 18850 - 18864. Retrieved 2018.
• 2、 Berton, Giacomo,Lorenzetto, Tommaso,Borsato, Giuseppe,Sgarbossa, Paolo,Santo, Claudio,Visentin, Fabiano,Fabris, Fabrizio,Scarso, Alessandro. "Triphenylene based metal-pyridine cages". supporting information. . Retrieved 2019/10/02.